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W(CO)3-


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 15000 ± 50 gas Bengali, Casey, et al., 1992

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 2 WCO bend 630 ± 10 gas PE Bengali, Casey, et al., 1992
4 CWC bend 100 ± 20 gas PE Bengali, Casey, et al., 1992
e CO stretch 1794.2 Ar IR Andrews, Zhou, et al., 2003

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bengali, Casey, et al., 1992
Bengali, A.A.; Casey, S.M.; Cheng, C.-L.; Dick, J.P.; Fenn, T.; Villaalta, P.W.; Leopold, D.G., Negative Ion Photoelectron Spectroscopy of Coordinatively Unsaturated Group VI Metal Carbonyls: Cr(CO)3, Mo(CO)3, and W(CO)3, J. Am. Chem. Soc., 1992, 114, 13, 5257, https://doi.org/10.1021/ja00039a043 . [all data]

Andrews, Zhou, et al., 2003
Andrews, L.; Zhou, M.; Gutsev, G.L., Reactions of Laser-Ablated Mo and W Atoms, Cations, and Electrons with CO in Excess Neon: Infrared Spectra and Density Functional Calculations on Neutral and Charged Unsaturated Metal Carbonyls, J. Phys. Chem. A, 2003, 107, 7, 990, https://doi.org/10.1021/jp026978v . [all data]


Notes

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