t,t,t-CF3OC(O)OO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 50000 T Ne von Ahsen, Willner, et al., 2002

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 41670 Ne von Ahsen, Willner, et al., 2002

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 C=O stretch 1903 Ne IR von Ahsen, Willner, et al., 2002
1 C=O stretch 1895 s Ar IR von Ahsen, Willner, et al., 2002
2 CF3 s-stretch 1298 Ne IR von Ahsen, Willner, et al., 2002
2 CF3 s-stretch 1295 vs Ar IR von Ahsen, Willner, et al., 2002
3 O-C stretch 1206 Ne IR von Ahsen, Willner, et al., 2002
3 O-C stretch 1206 m Ar IR von Ahsen, Willner, et al., 2002
4 Mixed 1174 Ne IR von Ahsen, Willner, et al., 2002
4 Mixed 1170 s Ar IR von Ahsen, Willner, et al., 2002
5 O-O stretch 1089 Ne IR von Ahsen, Willner, et al., 2002
5 O-O stretch 1087 m s Ar IR von Ahsen, Willner, et al., 2002
6 C-O2 stretch 938 Ne IR von Ahsen, Willner, et al., 2002
6 C-O2 stretch 936 w m Ar IR von Ahsen, Willner, et al., 2002
7 Mixed 894 Ne IR von Ahsen, Willner, et al., 2002
7 Mixed 895 w Ar IR von Ahsen, Willner, et al., 2002
8 CO3 deform. 740 Ne IR von Ahsen, Willner, et al., 2002
8 CO3 deform. 740 w Ar IR von Ahsen, Willner, et al., 2002
9 CF3 deform. 697 Ne IR von Ahsen, Willner, et al., 2002
9 CF3 deform. 694 w m Ar IR von Ahsen, Willner, et al., 2002
11 Mixed 401 w Ar IR von Ahsen, Willner, et al., 2002
a 15 CF3 a-stretch 1259 Ne IR von Ahsen, Willner, et al., 2002
15 CF3 a-stretch 1254 vs Ar IR von Ahsen, Willner, et al., 2002
16 CO3 deform. 720 Ne IR von Ahsen, Willner, et al., 2002
16 CO3 deform. 717 w m Ar IR von Ahsen, Willner, et al., 2002

Notes

wWeak
mMedium
sStrong
vsVery strong
TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

von Ahsen, Willner, et al., 2002
von Ahsen, S.; Willner, H.; Francisco, J.S., The Trifluoromethoxy Carbonyl Peroxy Radical CF3OC(O)OO, Chem. Eur. J., 2002, 8, 20, 4675, https://doi.org/10.1002/1521-3765(20021018)8:20<4675::AID-CHEM4675>3.0.CO;2-3 . [all data]

Notes

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