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FC(O)OC(O)F


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

C=O s-stretch 1941 m gas IR Bednarek, Arguello, et al., 1996
Goto, Kawasaki, et al., 2002
Pernice, Willner, et al., 2002
C=O a-stretch 1870 w m gas IR Pernice, Willner, et al., 2002
CF s-stretch 1249 w m gas IR Bednarek, Arguello, et al., 1996
Goto, Kawasaki, et al., 2002
Pernice, Willner, et al., 2002
COC a-stretch 1168 vs gas IR Goto, Kawasaki, et al., 2002
Pernice, Willner, et al., 2002
CF a-stretch 1030 w gas IR Pernice, Willner, et al., 2002
COC s-stretch 938 w gas IR Pernice, Willner, et al., 2002
Deformation 765 w gas IR Pernice, Willner, et al., 2002
FCO a-deform. 652 w gas IR Pernice, Willner, et al., 2002

Notes

wWeak
mMedium
vsVery strong

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bednarek, Arguello, et al., 1996
Bednarek, G.; Arguello, G.A.; Zeller, R., FTIR-Spectroscopic Study of Reactions of FCO and FC(O)OO Radicals in the Presence of O2 and NO2, Ber. Bunsenges. Phys. Chem., 1996, 100, 4, 445, https://doi.org/10.1002/bbpc.19961000408 . [all data]

Goto, Kawasaki, et al., 2002
Goto, M.; Kawasaki, M.; Wallington, T.J.; Hurley, M.D.; Sharratt, A.P., Atmospheric chemistry of CH2FOCH2F: Reaction with Cl atoms and atmospheric fate of CH2FOCHFO«65533» radicals, Int. J. Chem. Kinet., 2002, 34, 3, 139, https://doi.org/10.1002/kin.10038 . [all data]

Pernice, Willner, et al., 2002
Pernice, H.; Willner, H.; Bierbrauer, K.; Paci, M.B.; Arguello, G.A., Fluoroformic Acid Anhydride, FC(O)OC(O)F, Angew. Chem. Int. Ed., 2002, 41, 20, 3832, https://doi.org/10.1002/1521-3773(20021018)41:20<3832::AID-ANIE3832>3.0.CO;2-M . [all data]


Notes

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