CAl3Si

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   E
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 23240 ± 630 gas Li, Zhai, et al., 2003

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 19440 ± 630 gas Li, Zhai, et al., 2003

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 11620 ± 540 gas Wang, Boldyrev, et al., 2000
Li, Zhai, et al., 2003

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 5810 ± 540 gas Wang, Boldyrev, et al., 2000
Li, Zhai, et al., 2003

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 2100 ± 540 gas Wang, Boldyrev, et al., 2000
Li, Zhai, et al., 2003

Additional references: Jacox, 2003, page 279

Notes

xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Li, Zhai, et al., 2003
Li, X.; Zhai, H.-J.; Wang, L.S., Photoelectron spectroscopy of pentaatomic tetracoordinate planar carbon molecules: CAl3Si- and CAl3Ge-, Chem. Phys. Lett., 2003, 357, 5-6, 415, https://doi.org/10.1016/S0009-2614(02)00488-8 . [all data]

Wang, Boldyrev, et al., 2000
Wang, L.-S.; Boldyrev, A.I.; Li, X.; Simons, J., Experimental Observation of Pentaatomic Tetracoordinate Planar Carbon-Containing Molecules, J. Am. Chem. Soc., 2000, 122, 32, 7681, https://doi.org/10.1021/ja993081b . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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