NNBN

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 26350 Ar A-X 348 380 Travers and Gilbert, 2000
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Deformation 480 Ar AB Travers and Gilbert, 2000

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 NN stretch 2091.7 Ar IR Andrews, Hassanzadeh, et al., 1993
1 NN stretch 2100 ± 2 Ar IR Al-Jihad, Liu, et al., 1998
1 NN stretch 2124.8 N2 IR Hassanzadeh and Andrews, 1992
2 BN stretch 1802.0 Ar IR Andrews, Hassanzadeh, et al., 1993
2 BN stretch 1803 ± 2 Ar IR Al-Jihad, Liu, et al., 1998
2 BN stretch 1806.1 N2 IR Hassanzadeh and Andrews, 1992
3 N2-BN stretch 760.3 w Ar IR Andrews, Hassanzadeh, et al., 1993
3 N2-BN stretch 750.4 N2 IR Hassanzadeh and Andrews, 1992

Additional references: Jacox, 1994, page 184; Jacox, 2003, page 222

Notes

wWeak
oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Travers and Gilbert, 2000
Travers, M.J.; Gilbert, J.V., UV Absorption Spectra of Intermediates Generated via Photolysis of B(N, J. Phys. Chem. A, 2000, 104, 16, 3780, https://doi.org/10.1021/jp993939j . [all data]

Andrews, Hassanzadeh, et al., 1993
Andrews, L.; Hassanzadeh, P.; Burkholder, T.R.; Martin, J.M.L., Reactions of pulsed laser produced boron and nitrogen atoms in a condensing argon stream, J. Chem. Phys., 1993, 98, 2, 922, https://doi.org/10.1063/1.464256 . [all data]

Al-Jihad, Liu, et al., 1998
Al-Jihad, I.A.; Liu, B.; Linnen, C.J.; Gilbert, J.V., Generation of NNBN via Photolysis of B(N, J. Phys. Chem. A, 1998, 102, 31, 6220, https://doi.org/10.1021/jp9812684 . [all data]

Hassanzadeh and Andrews, 1992
Hassanzadeh, P.; Andrews, L., Pulsed laser-assisted reactions of boron and nitrogen atoms in a condensing nitrogen stream, J. Phys. Chem., 1992, 96, 23, 9177, https://doi.org/10.1021/j100202a020 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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