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AlSiH4


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   «lambda»min 
 (nm) 
 «lambda»max 
 (nm) 
 References

Td = 24400 Ar Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a1 1 SiH stretch 2181.1 Ar IR Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004
2 SiH stretch 2131.4 Ar IR Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004
4 Deformation 892.4 Ar IR Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004
b1 7 SiH stretch 2174.5 Ar IR Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004
b2 11 Deformation 901.7 Ar IR Gaertner and Himmel, 2002
Gaertner, Himmel, et al., 2004

Notes

dPhotodissociation threshold

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gaertner and Himmel, 2002
Gaertner, B.; Himmel, H.-J., Characterization and Photochemistry of the Silane-Aluminum Complex Al*SiH, Angew. Chem. Int. Ed., 2002, 41, 9, 1538, https://doi.org/10.1002/1521-3773(20020503)41:9<1538::AID-ANIE1538>3.0.CO;2-K . [all data]

Gaertner, Himmel, et al., 2004
Gaertner, B.; Himmel, H.-J.; Macrae, V.A.; Downs, A.J.; Greene, T.M., Matrix Reactivity of Al and Ga Atoms (M) in the Presence of Silane: Generation and Characterization of the«eta»2-Coordinated Complex M*SiH4, the Insertion Product HMSiH3, and the MI Species MSiH3 in a Solid Argon Matrix, Chem. Eur. J., 2004, 10, 14, 3430, https://doi.org/10.1002/chem.200305493 . [all data]


Notes

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