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Reaction data

(Sodium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) bullet 2Dimethyl ether)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

DeltarH° (kJ/mol) Method Reference Comment
89.5 ± 4.6CIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
83.7 ± 4.6CIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
88.7 ± 5.9CIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
82.0 ± 4.6CIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
86.6 ± 5.9CIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
82.0 ± 5.0CIDTRodgers and Armentrout, 2000RCD
79.1 ± 5.0CIDTMore, Ray, et al., 1997RCD

References

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Amicangelo and Armentrout, 2001
Amicangelo, J.C.; Armentrout, P.B., Relative and Absolute Bond Dissociation Energies of Sodium Cation Complexes Determined Using Competitive Collision-Induced Dissociation Experiments, Int. J. Mass Spectrom., 2001, 212, 1-3, 301, https://doi.org/10.1016/S1387-3806(01)00494-8 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

More, Ray, et al., 1997
More, M.B.; Ray, D.; Armentrout, P.B., Cation-ether complexes in the gas phase: Bond dissociation energies of Na+(dimethyl ether)(x), x=1-4; Na+(1,2-dimethoxyethane)(x), x=1 and 2; and Na+(12-crown-4), J. Phys. Chem. AJOURNAL OF PHYSICAL CHEMISTRY A 101 (5): 831-839 JAN 30 1997, 1997, 101, 831. [all data]


Notes

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