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Reaction data

(Chlorine anion bullet Water) + Water = (Chlorine anion bullet 2Water)


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

DeltarH° (kJ/mol) Method Reference Comment
57.74N/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
54.4 ± 4.2TDAsHiraoka and Mizuse, 1987gas phase; B
48.5 ± 2.1ZTIDDunbar, McMahon, et al., 1995gas phase; B,M,M
54. ± 2.PHPMSHiraoka, Mizuse, et al., 1988gas phase; M
52.72TDAsKeesee and Castleman, 1980gas phase; B,M
53.1 ± 4.2TDAsPayzant, Yamdagni, et al., 1971gas phase; B
53.1 ± 4.2TDAsArshadi, Yamdagni, et al., 1970gas phase; B,M

References

Go To: Top, Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Markovich, Pollack, et al., 1994
Markovich, G.; Pollack, S.; Giniger, R.; Cheshnovsky, O., Photoelectron spectroscopy of Cl-, Br-, and I- solvated in water clusters, J. Chem. Phys., 1994, 101, 11, 9344, https://doi.org/10.1063/1.467965 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

Dunbar, McMahon, et al., 1995
Dunbar, R.C.; McMahon, T.B.; Thölmann, D.; Tonner, D.S.; Salahub, D.R.; Wei, D., Zero-Pressure Thermal-Radiation-Induced Dissociation of Gas-Phase Cluster Ions: Comparison of Theory and Experiment for (H2O)2Cl- and (H2O)3Cl-, J. Am. Chem. Soc., 1995, 117, 51, 12819, https://doi.org/10.1021/ja00156a020 . [all data]

Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S., Solvation of Halide Ions with H2O and CH3CN in the Gas Phase, J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051 . [all data]

Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr., Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase, Chem. Phys. Lett., 1980, 74, 139. [all data]

Payzant, Yamdagni, et al., 1971
Payzant, J.D.; Yamdagni, R.; Kebarle, P., Hydration of CN-, NO2-, NO3-, and HO- in the gas phase, Can. J. Chem., 1971, 49, 3308. [all data]

Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P., Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions, J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014 . [all data]


Notes

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