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Schulze, C.; Schwarz, H., Kinetic Isotope Effects as a Mechanistic Tool for the Elucidation of the Rate-Determining Step(s) in the Transition Metal Ion-Mediated Activation of CH/CC Bonds. Ethylene Loss from Metastable 4-Octyne/M+ Complexes in the Gas Phase, Angew. Chem. Int. Ed. Engl., 1990, 29, 5, 509, https://doi.org/10.1002/anie.199005091 . [all data]