Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

Search Results

Search criteria:

Author:Downs, A.J.

You may also wish to search for items by Downs, A. and Downs.

41 matching references were found.

Downs, A.J.; Egdell, R.G.; Orchard, A.F.; Thomas, P.D.P., Photoelectron spectra of metal tetrahydroborates, J. Chem. Soc. Dalton Trans., 1978, 12, 1755. [all data]

Findlay, R.H.; Palmer, M.H.; Downs, A.J.; Egdell, R.G.; Evans, R., Electronic structure of the sulfur nitrides. Ab initio calculations and photoelectron spectra, Inorg. Chem., 1980, 19, 1307. [all data]

Downs, A.J., 846. Thiocarbonyl fluoride, J. Chem. Soc., 1962, 4361, https://doi.org/10.1039/jr9620004361 . [all data]

Downs, A.J.; Adams, G.J., , BOOK (1973), 1543. [all data]

Downs, A.J.; Adams, G.J., Comprehensive Inorganic Chemistry, J. C. Bailar, H. J. Emeleus, R. Nyholm and A. F. Trotman - Dickerson, ed(s)., Pergamon Press, New York, 1973, 1543. [all data]

Almond, M.J.; Downs, A.J., J. Chem. Soc., 1988, Dalton Trans. 809. [all data]

Appelman, E.H.; Downs, A.J.; Gardner, C.J., Matrix photochemistry of hypofluorous acid, HOF: oxygen atom transfer and other reactions, J. Phys. Chem., 1989, 93, 2, 598, https://doi.org/10.1021/j100339a021 . [all data]

Almond, M.J.; Downs, A.J.; Perutz, R.N., Matrix photooxidation of the metal carbonyls M(CO)6 (M = Cr, W) by the isoelectronic molecules carbon dioxide and nitrous oxide, Inorg. Chem., 1985, 24, 3, 275, https://doi.org/10.1021/ic00197a007 . [all data]

Burczyk, K.; Downs, A.J., J. Chem. Soc., 1990, Dalton Trans. 2351. [all data]

Downs, A.J.; Greene, T.M.; Johnsen, E.; Brain, P.T.; Morrison, C.A.; Parsons, S.; Pulham, C.R.; Rankin, D.W.H.; Aarset, K., et al., Preparation and Properties of Gallaborane, GaBH, Inorg. Chem., 2001, 40, 14, 3482, https://doi.org/10.1021/ic001338x . [all data]

Downs, A.J.; Goode, M.J.; Pulham, C.R., Gallane at last! Synthesis and properties of binary gallium hydride, J. Am. Chem. Soc., 1989, 111, 5, 1936, https://doi.org/10.1021/ja00187a090 . [all data]

Dyke, J.M.; Haggerston, D.; Warschkow, O.; Andrews, L.; Downs, A.J.; Souter, P.F., UV Photoelectron Spectra of the «mu»-Hydrido Bridge-Bonded Molecules B, J. Phys. Chem., 1996, 100, 8, 2998, https://doi.org/10.1021/jp953039c . [all data]

Fanfarillo, M.; Downs, A.J.; Greene, T.M.; Almond, M.J., Photooxidation of matrix-isolated iron pentacarbonyl. 2. Binary iron oxide reaction products and the overall reaction mechanism, Inorg. Chem., 1992, 31, 13, 2973, https://doi.org/10.1021/ic00039a054 . [all data]

Greene, T.M.; Andrews, L.; Downs, A.J., The Reaction of Zinc, Cadmium, and Mercury Atoms with Methane: Infrared Spectra of the Matrix-Isolated Methylmetal Hydrides, J. Am. Chem. Soc., 1995, 117, 31, 8180, https://doi.org/10.1021/ja00136a015 . [all data]

Greene, T.M.; Brown, W.; Andrews, L.; Downs, A.J.; Chertihin, G.V.; Runeberg, N.; Pyykko, P., Matrix Infrared Spectroscopic and ab Initio Studies of ZnH2, CdH2, and Related Metal Hydride Species, J. Phys. Chem., 1995, 99, 20, 7925, https://doi.org/10.1021/j100020a014 . [all data]

Gaertner, B.; Himmel, H.-J.; Macrae, V.A.; Downs, A.J.; Greene, T.M., Matrix Reactivity of Al and Ga Atoms (M) in the Presence of Silane: Generation and Characterization of the«eta»2-Coordinated Complex M*SiH4, the Insertion Product HMSiH3, and the MI Species MSiH3 in a Solid Argon Matrix, Chem. Eur. J., 2004, 10, 14, 3430, https://doi.org/10.1002/chem.200305493 . [all data]

Gaertner, B.; Himmel, H.-J.; Macrae, V.A.; Pardoe, J.A.J.; Randall, P.G.; Downs, A.J., Some Novel Binuclear Group 13 Metal Tin Hydrides Formed in Ar Matrices Following the Codeposition of the Metal Vapor with SnH4, Chem. Eur. J., 2004, 10, 22, 5836, https://doi.org/10.1002/chem.200400564 . [all data]

Greene, T.M.; Lanzisera, D.V.; Andrews, L.; Downs, A.J., A Matrix-Isolation and Density Functional Theory Study of the Reactions of Laser-Ablated Beryllium, Magnesium, and Calcium Atoms with Methane, J. Am. Chem. Soc., 1998, 120, 24, 6097, https://doi.org/10.1021/ja9804870 . [all data]

Hawkins, M.; Andrews, L.; Downs, A.J.; Drury, D.J., Photochemistry of an ozone molecular complex with iodine monochloride in cryogenic matrixes. The infrared spectra of iodosyl chloride (OICl) and iodyl chloride (O2ICl), J. Am. Chem. Soc., 1984, 106, 11, 3076, https://doi.org/10.1021/ja00323a002 . [all data]

Hawkins, M.; Almond, M.J.; Downs, A.J., Photochemistry of low-temperature matrixes containing carbonyl sulfide: reactions of sulfur atoms with the phosphorus trihalides phosphorus trifluoride (PF3) and phosphorus trichloride (PCl3) and the hydrocarbons methane, ethene, and ethyne, J. Phys. Chem., 1985, 89, 15, 3326, https://doi.org/10.1021/j100261a034 . [all data]

Hawkins, M.; Downs, A.J., The photochemistry of argon matrixes containing nitric oxide and carbonyl sulfide. 2. The photoproducts SNO and SN2O2, J. Phys. Chem., 1984, 88, 14, 3042, https://doi.org/10.1021/j150658a023 . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M.; Andrews, L., Chem. Commun., 1999, 2243. [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Formation and Characterization of the Indium Hydride Molecules H, J. Am. Chem. Soc., 2000, 122, 5, 922, https://doi.org/10.1021/ja9932333 . [all data]

Himmel, H.-J.; Downs, A.J.; Green, J.C.; Greene, T.M., Thermal and Photolytic Reactions of Gallium and Indium Atoms (M) and Their Dimers M, J. Phys. Chem. A, 2000, 104, 16, 3642, https://doi.org/10.1021/jp9938359 . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M.; Andrews, L., Matrix Photochemistry of Gallium and Indium Atoms (M) in the Presence of Methane: Formation and Characterization of the Divalent Species CH, Organomet., 2000, 19, 6, 1060, https://doi.org/10.1021/om990905p . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Chem. Commun., 2000, 871. [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Thermal and Photochemical Reactions of Aluminum, Gallium, and Indium Atoms (M) in the Presence of Ammonia: Generation and Characterization of the Species M·NH, J. Am. Chem. Soc., 2000, 122, 40, 9793, https://doi.org/10.1021/ja001313x . [all data]

Himmel, H.-J.; Downs, A.J.; Greene, T.M., Reactions of Aluminum, Gallium, and Indium (M) Atoms with Phosphine: Generation and Characterization of the Species M·PH, Inorg. Chem., 2001, 40, 2, 396, https://doi.org/10.1021/ic000837v . [all data]

Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Characterization and Photochemistry of the Gallium and Indium Subhydrides Ga2H2 and In2H2 This work was supported by the Deutsche Forschungsgemeinschaft (Habilitation grant to H.-J. H.), the CNRS (L. M.), and the EPSRC (A. J. D.)., Angew. Chem. Int. Ed., 2002, 41, 5, 796, https://doi.org/10.1002/1521-3773(20020301)41:5<796::AID-ANIE796>3.0.CO;2-3 . [all data]

Himmel, H.-J.; Manceron, L.; Downs, A.J.; Pullumbi, P., Formation and Characterization of the Gallium and Indium Subhydride Molecules Ga, J. Am. Chem. Soc., 2002, 124, 16, 4448, https://doi.org/10.1021/ja0122795 . [all data]

Kurth, F.A.; Eberlein, R.A.; Schnockel, H.; Downs, A.J.; Pulham, C.R., J. Chem. Soc., 1993, Chem. Commun. 1302. [all data]

Macrae, V.A.; Downs, A.J., Matrix studies of the thermal and photolytic reactions of Ga vapour species with H2O: formation and characterisation of the adducts Ga«65533»OH2 and Ga2«65533»OH2 and the photoproducts HGaOH, GaOH and Ga(«65533»-H)(«65533»-OH)GaElectronic supplementary information (ESI) available: UV?vis spectra of an Ar matrix containing Ga and H2O (Fig. S1); calculated and observed IR spectral details for Ga(«65533»-H)(«65533»-OH)Ga (Table S1). See http://www.rsc.org/suppdata/cp/b4/b405298f/, Phys. Chem. Chem. Phys., 2004, 6, 19, 4571, https://doi.org/10.1039/b405298f . [all data]

Macrae, V.A.; Greene, T.M.; Downs, A.J., Matrix Reactivity of Zn, Cd, or Hg Atoms (M) in the Presence of Silane: Photogeneration and Characterization of the Insertion Product HMSiH, J. Phys. Chem. A, 2004, 108, 8, 1393, https://doi.org/10.1021/jp0309769 . [all data]

Macrae, V.A.; Greene, T.M.; Downs, A.J., Matrix studies of the thermal and photolytic reactions of Zn, Cd and Hg (M) atoms with H2O: formation and characterisation of the adduct M?OH2 and photoproduct HMOHElectronic supplementary information (ESI) available: IR spectra of a matrix containing Hg and D2O (Fig. S1); calculated and observed IR spectra for M?OH2 species (M = Zn, Cd or Hg) (Table S1). See http://www.rsc.org/suppdata/cp/b4/b405300a/, Phys. Chem. Chem. Phys., 2004, 6, 19, 4586, https://doi.org/10.1039/b405300a . [all data]

Macrae, V.A.; Green, J.C.; Greene, T.M.; Downs, A.J., Thermal and Photolytic Reactions of Group 12 Metal Atoms in HCl-Doped Argon Matrixes: Formation and Characterization of the Hydride Species HMCl (M = Zn, Cd, or Hg), J. Phys. Chem. A, 2004, 108, 44, 9500, https://doi.org/10.1021/jp040010c . [all data]

Peake, S.C.; Downs, A.J., J. Chem. Soc., 1974, Dalton Trans., 859. [all data]

Pulham, C.R.; Downs, A.J.; Goode, M.J.; Rankin, D.W.H.; Robertson, H.E., Gallane: synthesis, physical and chemical properties, and structure of the gaseous molecule Ga2H6 as determined by electron diffraction, J. Am. Chem. Soc., 1991, 113, 14, 5149, https://doi.org/10.1021/ja00014a003 . [all data]

Pulham, C.R.; Downs, A.J.; Goode, M.J.; Mills, I.M., Spectrochim. Acta, 1995, 51A, 769. [all data]

Romano, R.M.; Della Vedova, C.O.; Downs, A.J.; Greene, T.M., Matrix Photochemistry of, J. Am. Chem. Soc., 2001, 123, 24, 5794, https://doi.org/10.1021/ja010252f . [all data]

Romano, R.M.; Della Vedova, C.O.; Downs, A.J., Matrix Photochemistry of the Chlorocarbonyl Sulfenyl Compounds ClC(O)SY, with Y = Cl or CH, J. Phys. Chem. A, 2004, 108, 35, 7179, https://doi.org/10.1021/jp048756y . [all data]

Souter, P.F.; Andrews, L.; Downs, A.J.; Greene, T.M.; Ma, B.; Schaefer, H.F., III, Observed and calculated Raman spectra of the Ga2H6 and Ga2D6 molecules, J. Phys. Chem., 1994, 98, 49, 12824, https://doi.org/10.1021/j100100a004 . [all data]