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Author:Cossar, J.

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Guthrie, J.P.; Cossar, J.; Klym, A., Halogenation of acetone. A method for determining pKaS of ketones in aqueous solution, with an examination of the thermodynamics and kinetics of alkaline halogenation and a discussion of the best value for the rate constant for a "diffusion-controlled reaction". Energetic requirements for a diffusion-controlled reaction involving heavy-atom bond formation, J. Am. Chem. Soc., 1984, 106, 1351-13. [all data]