Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

NOTICE: Due to scheduled maintenance at our Gaithersburg campus, this site will not be available from 5:00 pm EDT (21:00 UTC) on Friday October 25 until 5:00 pm (21:00 UTC) on Sunday October 27. We apologize for any inconvenience this outage may cause.

Search Results

Search criteria:

Author:Brauman, J.

You may also wish to search for items by Brauman.

71 matching references were found.

Brauman, J.I.; Blair, L.K., Gas phase acidities of amines, J. Am. Chem. Soc., 1971, 93, 3911. [all data]

Smyth, K.C.; McIver, R.T.; Brauman, J.I.; Wallace, R.W., Photodetachment of negative ions using a continuously tunable laser and an ICR spectrometer, J. Chem. Phys., 1971, 54, 2758. [all data]

Smyth, K.C.; Brauman, J.I., Photodetachment of electrons from phosphide ion the electron affinity of PH2-, J. Chem. Phys., 1972, 56, 1132. [all data]

Smyth, K.C.; Brauman, J.I., Photodetachment of electrons from amide and arsenide ions: The electron affinities of NH2 and AsH2., J. Chem. Phys., 1972, 56, 4620. [all data]

Smyth, K.C.; Brauman, J.I., Photodetachment of an electron from selenide ion the electron affinity and spin- orbit coupling constant for SeH, J. Chem. Phys., 1972, 56, 5993. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from large molecular systems: Cyclopentadienide and methylcyclopentadienide ions. An upper limit to the electron affinities of C5H5 and CH3C5H4, J. Chem. Phys., 1973, 59, 5068. [all data]

Pearson, P.K.; Schaefer, H.F., III; Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Three isomers of the NO2- ion, J. Am. Chem. Soc., 1974, 96, 6778. [all data]

Reed, K.J.; Brauman, J.I., Photodetachment of electrons from Group IVa binary hydride anions: The electron affinities of the SiH3 and GeH3 radicals, J. Chem. Phys., 1974, 61, 4830. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of NO2-: Experimental evidence for a new isomer, Chem. Phys. Lett., 1974, 25, 318. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from phenoxides and thiophenoxide, Chem. Phys. Lett., 1974, 25, 321. [all data]

Asubiojo, O.I.; Blair, L.K.; Brauman, J.I., Tetrahedral intermediates in gas phase ionic displacement reactions at carbonyl carbons, J. Am. Chem. Soc., 1975, 97, 6685. [all data]

Reed, K.J.; Brauman, J.I., Electron affinities of alkoxy radicals and the bond dissociation energies in aliphatic alcohols, J. Am. Chem. Soc., 1975, 97, 1625. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from large molecular systems: Benzyl anion. An upper Limitlto the electron affinity of C6H5CH2, J. Chem. Phys., 1975, 63, 74. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from phenoxides and thiophenoxide, J. Am. Chem. Soc., 1975, 97, 2967. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from large molecular systems. Pyrrolate ion. Electron affinity of C4H4N, J. Am. Chem. Soc., 1975, 97, 1160. [all data]

Richardson, J.H.; Stephenson, L.M.; Brauman, J.I., Photodetachment of electrons from trifluoromethyl and trifluorosilyl ions the electron affinities of CF3 and SiF3, Chem. Phys. Lett., 1975, 30, 17. [all data]

Zimmerman, A.H.; Brauman, J.I., Electron photodetachment from negative ions of C2v symmetry. Electron affinities of allyl and cyanomethyl radicals, J. Am. Chem. Soc., 1977, 99, 3565. [all data]

Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Photodetachment of electrons from enolate anions. Gas phase electron affinities of enolate radicals, J. Am. Chem. Soc., 1977, 99, 7203. [all data]

Janousek, B.K.; Zimmerman, A.H.; Reed, K.J.; Brauman, J.I., Electron detachment from aliphatic molecular anions. Gas phase electron affinites of methoxyl, tert-butoxyl, and neopentoxyl radicals, J. Am. Chem. Soc., 1978, 100, 6142. [all data]

Zimmerman, A.H.; Gygax, R.; Brauman, J.I., Electron photodetachment spectroscopy of polyene anions. Electron affinities of pentadienyl and heptatrienyl radicals, J. Am. Chem. Soc., 1978, 100, 5595. [all data]

Gygax, R.; Peters, H.L.; Brauman, J.I., Photodetachment of electrons from anions of high symmetry. Electron photodetachment spectra of the cycloctatetraenyl and perinaphthenyl anions, J. Am. Chem. Soc., 1979, 101, 2567. [all data]

Janousek, B.K.; Brauman, J.I.; Simons, J., An experimental and theoretical determination of the electron affinity of the enhynyl radical HC2, J. Chem. Phys., 1979, 71, 2057. [all data]

Janousek, B.K.; Brauman, J.I., Electron photodetachment of thiomethoxyl and deuterothiomethoxyl anions: Electron affinities, vibrational frequencies, and spin-orbit splitting in CH3S- and CD3S-, J. Chem. Phys., 1980, 72, 694. [all data]

Janousek, B.K.; Reed, K.J.; Brauman, J.I., Electron photodetachment from mercaptyl anions (RS- electron affinities of mercaptyl radicals and the S-H bond strength in mercaptans), J. Am. Chem. Soc., 1980, 102, 3125. [all data]

Jackson, R.L.; Pellerite, M.J.; Brauman, J.I., Photodetachment of the azide ion in the gas phase. Electron affinity of the azide radical, J. Am. Chem. Soc., 1981, 103, 1802. [all data]

Pellerite, M.J.; Jackson, R.L.; Brauman, J.I., Proton affinity of the gaseous azide Ion. The N-H bond dissociation enegry in HN3, J. Phys. Chem., 1981, 85, 1624. [all data]

Drzaic, P.S.; Brauman, J.I., Electron photodetachment of sulfur hexafluoride anion. Comments on the structure of SF6-, J. Am. Chem. Soc., 1982, 104, 13. [all data]

Drzaic, P.S.; Brauman, J.I., A determination of the singlet-triplet splitting in phenylnitrene via photoelectron detachment, J. Am. Chem. Soc., 1984, 106, 3443. [all data]

Drzaic, P.S.; Brauman, J.I., A determination of the singlet-triplet splitting in phenylnitrene via photoelectron detachment, J. Phys. Chem., 1984, 88, 5285. [all data]

Moyland, C.R.; Brauman, J.I., Bond dissociation energies in alcohols: Kinetic and photochemical evidence regarding ion thermochemistry, J. Phys. Chem., 1984, 88, 3175. [all data]

Tumas, W.; Foster, R.F.; Brauman, J.I., Unimolecular decompositions of gas-phase alkoxide anions, J. Am. Chem. Soc., 1984, 106, 4053. [all data]

Illenberger, E.; Comita, P.; Brauman, J.I.; Fenzlaff, H.-P.; Heni, M.; Heinrich, N.; Koch, W.; Frenking, G., Experimental and theoretical investigation of the azide anion (N3-) in the gas phase, Ber. Bunsen-Ges. Phys. Chem., 1985, 89, 1026. [all data]

Marks, J.; Comita, P.B.; Brauman, J.I., Threshold resonances in electron photodetachment spectra. Structural evidence for dipole-supported states, J. Am. Chem. Soc., 1985, 107, 3718. [all data]

Moylan, C.R.; Dodd, J.A.; Brauman, J.I., Electron photodetachment spectroscopy of Sslvated anions. A probe of structure and energetics, Chem. Phys. Lett., 1985, 118, 38. [all data]

Marks, J.; Wetzel, D.M.; Comita, P.B.; Brauman, J.I., A dipole supported state in cyanomethyl anion, the conjugate base of acetonitrile. Rotational band assignments in the electron photodetachment spectrum of -CH2CN, J. Chem. Phys., 1986, 84, 5284. [all data]

Pellerite, M.J.; Brauman, J.I., Gas-phase ion-molecule reactions of phenylnitrene anion, J. Am. Chem. Soc., 1991, 103, 676-677. [all data]

Janousek, B.; Brauman, J.I., Electron Affinities in Gas Phase Ion Chemistry, Gas Phase Ion Chemistry, V. 2, M.T. Bowers, Ed., Academic Press, NY, 1979, Ch. 10, Elsevier, 1979. [all data]

Drzaic, P.S.; Marks, J.; Brauman, J.I., Electron Photodetachment from Gas Phase Molecular Anions in Ions and Light, Gas Phase Ion Chemistry, V. 3, M.T. Bowers, Ed., Academic Press, NY, 1984, Ch. 21, Elsevier, 1984. [all data]

Angelini, G.; Johnson, C.E.; Brauman, J.I., Addition and Deprotonation in Reactions of Hydroxide Ion with a beta-Hydroxysilane, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 1, https://doi.org/10.1016/0168-1176(91)85093-2 . [all data]

Brauman, J.I.; Blair, L.K., Gas Phase Acidities of Carbon Acids, J. Am. Chem. Soc., 1968, 90, 20, 5636, https://doi.org/10.1021/ja01022a073 . [all data]

Brauman, J.I.; Blair, L.K., Gas Phase Acidities of Alcohols. Effect of Alkyl Groups, J. Am. Chem. Soc., 1968, 90, 23, 6561, https://doi.org/10.1021/ja01025a083 . [all data]

Han, C.-C.; Brauman, J.I., Electron Transfer Competes with Proton Transfer in Gas-phase Acid-base Reactions, J. Am. Chem. Soc., 1988, 110, 12, 4048, https://doi.org/10.1021/ja00220a059 . [all data]

Wetzel, D.M.; Brauman, J.I., Quantitative Measure of alpha-Silyl Carbanion Stabilization. The Electron Affinity of (Trimethylsilyl)methyl Radical, J. Am. Chem. Soc., 1988, 110, 25, 8333, https://doi.org/10.1021/ja00233a008 . [all data]

Wetzel, D.M.; Salomon, K.E.; Berger, S.; Brauman, J.I., Gas-Phase Acidities of Organosilanes and Electron Affinities of Organosilyl Radicals, J. Am. Chem. Soc., 1989, 111, 11, 3835, https://doi.org/10.1021/ja00193a013 . [all data]

Baer, S.; Brinkman, E.A.; Brauman, J.I., Hemiacetal Anions: A Model for Tetrahedral Reaction Intermediates, J. Am. Chem. Soc., 1991, 113, 3, 805, https://doi.org/10.1021/ja00003a012 . [all data]

Brinkman, E.A.; Berger, S.; Brauman, J.I., alpha-Silyl-substituent stabilization of carbanions and silyl anions, J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042 . [all data]

Brinkman, E.A.; Salomon, K.; Tumas, W.; Brauman, J.I., Electron affinities and gas-phase acidities of organogermanium and organotin compounds, J. Am. Chem. Soc., 1995, 117, 17, 4905, https://doi.org/10.1021/ja00122a022 . [all data]

Mihalick, J.E.; Gatev, G.G.; Brauman, J.I., Electron Photodetachment Spectroscopy of Solvated Anions: RO.HF- or ROH.F-?, J. Am. Chem. Soc., 1996, 118, 49, 12424, https://doi.org/10.1021/ja954202k . [all data]

Römer, B.C.; Brauman, J.I., Electron Photodetachment Spectroscopy of (E) and (Z)-Propionaldehyde Enolate Anions. Electron Affinities of the Stereoisomers of Propionaldehyde Enolate Radicals., J. Am. Chem. Soc., 1997, 119, 8, 2054, https://doi.org/10.1021/ja962482d . [all data]

Römer, B.; Janaway, G.; Brauman, J.I., Cyclopentadienyl, Indenyl, and Fluorenyl Anions: Gas-Phase and Solvation Energy Contributions to Electron Detachment Energies, J. Am. Chem. Soc., 1997, 119, 9, 2249, https://doi.org/10.1021/ja961947x . [all data]

Janaway, G.A.; Zhong, M.; Gatev, G.G.; Chabinyc, M.L.; Brauman, J.I., [FHNO]-: An Intermediate in a Spin-Forbidden Proton Transfer Reaction, J. Am. Chem. Soc., 1997, 119, 48, 11697, https://doi.org/10.1021/ja9726872 . [all data]

Chabinyc, M.L.; Brauman, J.I., Acidity, basicity, and the stability of hydrogen bonds: Complexes of RO-+HCF3, J. Am. Chem. Soc., 1998, 120, 42, 10863-10870, https://doi.org/10.1021/ja9817592 . [all data]

Romer, B.; Gatev, G.G.; Zhong, M.; Brauman, J.I., Alpha-Stabilization by Silyl and Phosphino Substitution, J. Am. Chem. Soc., 1998, 120, 12, 2919, https://doi.org/10.1021/ja970279s . [all data]

Chabinyc, M.L.; Brauman, J.I., Unusual ionic hydrogen bonds: Complexes of acetylides and fluoroform, J. Am. Chem. Soc., 2000, 122, 36, 8739-8745, https://doi.org/10.1021/ja000806z . [all data]

Karty, J.M.; Wu, Y.S.; Brauman, J.I., The RS-center dot HSR hydrogen bond: Acidities of alpha,omega- dithiols and electron affinities of their monoradicals, J. Am. Chem. Soc., 2001, 123, 40, 9800-9805, https://doi.org/10.1021/ja0039684 . [all data]

Chen, X.; Walthall, D.A.; Brauman, J.I., Acidities in cyclohexanediols enhanced by intramolecular hydrogen bonds, J. Am. Chem. Soc., 2004, 126, 39, 12614-12620, https://doi.org/10.1021/ja049780s . [all data]

Jackson, R.L.; Hiberty, P.C.; Brauman, J.I., Threshold Resonances in the Electron Photodetachment spectrum of Acetaldehyde Anion. Evidence for a low-lying Dipole Supported State., J. Chem. Phys., 1981, 74, 7, 3705, https://doi.org/10.1063/1.441598 . [all data]

Moylan, C.R.; Dodd, J.A.; Han, C.-C.; Brauman, J.I., Spectroscopy of Reactive Intermediates: Electron Photodetachment from Solvated Anions, J. Chem. Phys., 1987, 86, 10, 5350, https://doi.org/10.1063/1.452560 . [all data]

Marks, J.; Brauman, J.I.; Mead, R.D.; Lykke, K.R.; Lineberger, W.C., Spectroscopy and Dynamics of the Dipole Supported State of Acetyl Fluoride Enolate Anion, J. Chem. Phys., 1988, 88, 11, 6785, https://doi.org/10.1063/1.454424 . [all data]

Brinkman, E.A.; Gunther, E.; Schafer, O.; Brauman, J.I., Bound Excited Electronic States of Anions, J. Chem. Phys., 1994, 100, 3, 1840, https://doi.org/10.1063/1.466535 . [all data]

Wladkowski, B.D.; East, A.L.L.; Mihalick, J.E.; Allen, W.D.; Brauman, J.I., The Proton-Transfer Surface of Ch3OHF-, J. Chem. Phys., 1994, 100, 3, 2058, https://doi.org/10.1063/1.466506 . [all data]

Mead, R.D.; Lykke, K.R.; Lineberger, W.C.; Marks, J.; Brauman, J.I., Spectroscopy and Dynamics of the Dipole-Bound State of Acetaldehyde Enolate., J. Chem. Phys., 1984, 81, 11, 4883., https://doi.org/10.1063/1.447515 . [all data]

Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I., Molecular Rotation and the Observation of Dipole-Bound States of Anions, J. Chem. Phys., 1993, 99, 10, 7586, https://doi.org/10.1063/1.465688 . [all data]

Chabinyc, M.L.; Brauman, J.I., Hydrogen bond strength and acidity. Structural and energetic correlations for acetylides and alcohols, J. Phys. Chem. A, 1999, 103, 46, 9163-9166, https://doi.org/10.1021/jp992852v . [all data]

Walthall, D.A.; Brauman, J.I., Vinyl hydrogen acidities of two stereoisomers, J. Phys. Chem. A, 2007, 111, 7, 1362-1367, https://doi.org/10.1021/jp0666075 . [all data]

Janousek, B.K.; Brauman, J.I., Electron Photodetachment from HS-. The Electron Affinity of HS, Phys. Rev. A, 1981, 23, 4, 1673, https://doi.org/10.1103/PhysRevA.23.1673 . [all data]

Brinkman, E.A.; Berger, S.; Marks, J.; Brauman, J.I., J. Chem. Phys., 2001, 99, 12675. [all data]

Wetzel, D.M.; Brauman, J.I., Rotational structure in an excited vibronic band of the dipole-supported state of cyanomethyl anion, CH2CN-, J. Chem. Phys., 1989, 90, 1, 68, https://doi.org/10.1063/1.456468 . [all data]

Janousek, B.K.; Brauman, J.I., Electron photodetachment from HS-. The electron affinity of HS, Phys. Rev. A: Gen. Phys., 1981, 23, 1673-1678. [all data]

Alms, G.R.; Bauer, D.R.; Brauman, J.I.; Pecora, R., Depolarized Rayleigh Scattering and Orientational Relaxation of Molecules in Solution. I. Benzene, Toluene, and p-Xylene, J. Chem. Phys., 1973, 58, 5570-5578. [all data]

Zimmerman, A.H.; Jackson, R.L.; Janousek, B.K.; Brauman, J.J., Electron photodetachment from cyclic enolate anions in the gas phase: Electron affinities of cyclic enolate radicals, J. Am. Chem. Soc., 1978, 100, 4674. [all data]