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Trimethylsilane


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

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Individual Reactions

C3H9Si- + Hydrogen cation = Trimethylsilane

By formula: C3H9Si- + H+ = C3H10Si

QuantityValueUnitsMethodReferenceComment
Deltar1614. ± 9.2kJ/molD-EAWetzel, Salomon, et al., 1989gas phase
Deltar1607. ± 17.kJ/molG+TSDamrauer, Kass, et al., 1988gas phase; Between furan and methanol.
QuantityValueUnitsMethodReferenceComment
Deltar1584. ± 9.6kJ/molH-TSWetzel, Salomon, et al., 1989gas phase
Deltar1577. ± 17.kJ/molIMRBDamrauer, Kass, et al., 1988gas phase; Between furan and methanol.
Deltar1565. ± 13.kJ/molIMRBGrimm and Bartmess, 1992gas phase
Deltar>1569. ± 13.kJ/molIMRBWetzel, Salomon, et al., 1989gas phase

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wetzel, Salomon, et al., 1989
Wetzel, D.M.; Salomon, K.E.; Berger, S.; Brauman, J.I., Gas-Phase Acidities of Organosilanes and Electron Affinities of Organosilyl Radicals, J. Am. Chem. Soc., 1989, 111, 11, 3835. [doi:10.1021/ja00193a013] [all data]

Damrauer, Kass, et al., 1988
Damrauer, R.; Kass, S.R.; DePuy, C.H., Gas-Phase Acidities of Methylsilanes: C-H versus Si-H, Organomet., 1988, 7, 3, 637. [doi:10.1021/om00093a011] [all data]

Grimm and Bartmess, 1992
Grimm, D.T.; Bartmess, J.E., The Intrinsic (Gas Phase) Basicity of some Anions Commonly Used in Condensed-Phase Synthesis, J. Am. Chem. Soc., 1992, 114, 4, 1227. [doi:10.1021/ja00030a016] [all data]


Notes

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