o-Terphenyl

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
liquid337.11J/mol*KN/AChang and Bestul, 1972DH
Quantity Value Units Method Reference Comment
Δfsolid179.8 ± 3.1kJ/molReviewRoux, Temprado, et al., 2008There are sufficient literature values to make a qualified recommendation where the suggested value is in good agreement with values predicted using thermochemical cycles or from reliable estimates. In general, the evaluated uncertainty limits are on the order of (2 to 4) kJ/mol.; DRB
Quantity Value Units Method Reference Comment
solid,1 bar298.81J/mol*KN/AChang and Bestul, 1972DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
369.05298.15Chang and Bestul, 1972T = 250 to 360 K. Supercooled liquid below Tm 329.35 K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
274.75298.15Chang and Bestul, 1972T = 2 to 350 K. Also data for annealed and quenched glass.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chang and Bestul, 1972
Chang, S.S.; Bestul, A.B., Heat capacity and thermodynamic properties of o-terphenyl crystal, glass and liquid, J. Chem. D Phys., 1972, 56, 503-516. [all data]

Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y., Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]


Notes

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