Bicyclo(3.2.1)oct-2-ene


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C8H12+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
8.76 ± 0.02PIDemeo and El-Sayed, 1970RDSH

De-protonation reactions

C8H11- + Hydrogen cation = Bicyclo(3.2.1)oct-2-ene

By formula: C8H11- + H+ = C8H12

Quantity Value Units Method Reference Comment
Δr1634.4 ± 3.6kJ/molG+TSLee and Squires, 1986gas phase; B
Quantity Value Units Method Reference Comment
Δr1603.7 ± 2.5kJ/molIMRELee and Squires, 1986gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Demeo and El-Sayed, 1970
Demeo, D.A.; El-Sayed, M.A., Ionization potential and structure of olefins, J. Chem. Phys., 1970, 52, 2622. [all data]

Lee and Squires, 1986
Lee, R.E.; Squires, R.R., Anionic homoaromaticity: A gas phase experimental study, J. Am. Chem. Soc., 1986, 105, 5078. [all data]


Notes

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