Silver chloride
- Formula: AgCl
- Molecular weight: 143.321
- IUPAC Standard InChI: InChI=1S/Ag.ClH/h;1H/q+1;/p-1
- IUPAC Standard InChIKey: HKZLPVFGJNLROG-UHFFFAOYSA-M
- CAS Registry Number: 7783-90-6
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to AgCl+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.3 ± 0.5 | EI | Wagner and Grimley, 1972 | LLK |
| 10.8 ± 0.4 | EI | Graber and Weil, 1972 | LLK |
| 10.3 ± 0.4 | EI | Visnapuu and Jensen, 1970 | RDSH |
| 10.5 ± 0.3 | EI | Hildenbrand, 1970 | RDSH |
| 10.08 | PE | Berkowitz, Batson, et al., 1980 | Vertical value; LLK |
| 10.14 | PE | Berkowitz, Batson, et al., 1980 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Ag+ | 11.1 ± 0.3 | ? | EI | Graber and Weil, 1972 | LLK |
| Ag+ | 11.0 ± 0.4 | Cl | EI | Visnapuu and Jensen, 1970 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wagner and Grimley, 1972
Wagner, L.C.; Grimley, R.T.,
A study of ionization processes by the angular distribution technique. The AgCl system,
J. Phys. Chem., 1972, 76, 2819. [all data]
Graber and Weil, 1972
Graber, P.; Weil, K.G.,
Mass spectrometric investigations of silver halides I: mass spectrum, appearance potentials, fragmentation scheme of silver chloride,
Ber. Bunsen-Ges. Phys. Chem., 1972, 76, 410. [all data]
Visnapuu and Jensen, 1970
Visnapuu, A.; Jensen, J.W.,
Composition and properties of vapors over molten silver chloride,
J.Less-Common Metals, 1970, 20, 141. [all data]
Hildenbrand, 1970
Hildenbrand, D.L.,
Dissociation energies and chemical bonding in the alkaline-earth chlorides from mass spectrometric studies,
J. Chem. Phys., 1970, 52, 5751. [all data]
Berkowitz, Batson, et al., 1980
Berkowitz, J.; Batson, C.H.; Goodman, G.L.,
Photoelectron spectroscopy of AgCl, AgBr, and AgI vapors,
J. Chem. Phys., 1980, 72, 5829. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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