Camphor

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Normal alkane RI, polar column, temperature ramp

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxCP-Wax 52 CBDB-WaxBP-20Supelcowax-10
Column length (m) 60.60.30. 30.
Carrier gas HeliumHeliumHeliumNitrogenHelium
Substrate      
Column diameter (mm) 0.250.250.25 0.20
Phase thickness (μm) 0.250.250.25 0.20
Tstart (C) 60.40.40.60.70.
Tend (C) 220.220.230.200.220.
Heat rate (K/min) 3.3.4.5.3.
Initial hold (min) 1. 2.  
Final hold (min) 5. 4.5 15.
I 1531.1516.1536.1512.1511.
ReferenceFeng, Zhuang, et al., 2011Tsai, Huang, et al., 2011Zeng, Xie, et al., 2011Mishra, Chaudhary, et al., 2010Neves, Rosa, et al., 2010
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase RTX-WaxHP-InnowaxHP-InnowaxCP Wax 52 CBCarbowax
Column length (m) 60.50.30.60.60.
Carrier gas HeliumHeliumN2HeliumHe
Substrate      
Column diameter (mm) 0.220.200.250.250.2
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 60.45.50.40.60.
Tend (C) 230.190.240.220.250.
Heat rate (K/min) 2.4.5.3.2.
Initial hold (min)  2.1. 8.
Final hold (min) 30.50.4. 15.
I 1490.1529.1473.1496.1514.
ReferenceMuseli, Pau, et al., 2009Soria, Sanz, et al., 2008Cheraif, Ben Jannet, et al., 2007Chen, Chyau, et al., 2007Ferhat, Meklati, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Wax 52CBHP-20MTC-FFAPSupelcowax-10Supelcowax-10
Column length (m) 30.50. 30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.320.20.250.20.25
Phase thickness (μm) 0.250.20.250.20.25
Tstart (C) 40.70.60.70.50.
Tend (C) 220.180.220.220.250.
Heat rate (K/min) 3.4.3.3.2.
Initial hold (min) 1.4.   
Final hold (min) 2. 30.15. 
I 1486.1472.1522.1515.1508.
ReferenceHymete, Rohloff, et al., 2007Jerkovic, Mastelic, et al., 2007Kurose, Okamura, et al., 2007Pinto, Salgueiro, et al., 2007Raal, Orav, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10InnowaxInnowaxSupelcowax 10FFAP
Column length (m) 30.30.30.30.20.
Carrier gas HeN2N2HeliumHe
Substrate      
Column diameter (mm) 0.250.250.250.200.25
Phase thickness (μm) 0.250.250.250.200.25
Tstart (C) 40.50.50.70.90.
Tend (C) 250.280.280.220.250.
Heat rate (K/min) 3.9.9.3.6.
Initial hold (min) 5.3.3.  
Final hold (min) 10.3.3.15. 
I 1495.1519.1532.1515.1560.
ReferenceVichi, Riu-Aumatell, et al., 2007Abdelwahed, Hayder, et al., 2006Abdelwahed, Hayder, et al., 2006Cavaleiro, Pinto, et al., 2006Kitchlu, Bakshi, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-WaxHP-20MDB-InnowaxSupelcowax-10Innowax
Column length (m) 30.30.60.30.50.
Carrier gas NitrogenN2HeliumHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.250.250.250.5
Tstart (C) 50.50.60.50.60.
Tend (C) 280.250.240.250.250.
Heat rate (K/min) 5.5.3.4.2.
Initial hold (min)    1. 
Final hold (min) 5.10.20.10.60.
I 1509.1509.1518.1499.1520.
ReferenceMarzouk, Mansour, et al., 2006Marzouk, Neffati, et al., 2006Mendivil, Rodrigues, et al., 2006Wong, Sivasothy, et al., 2006Bendimerad and Bendiab, 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-InnowaxHP-20MCarbowax 20MInnowaxDB-Wax
Column length (m) 30.50.50.60.30.
Carrier gas HeliumHeliumHeliumHeHe
Substrate      
Column diameter (mm) 0.250.200.250.250.25
Phase thickness (μm) 0.250.200.250.250.25
Tstart (C) 80.70.40.60.50.
Tend (C) 260.250.190.240.180.
Heat rate (K/min) 5.4.4.5.3.
Initial hold (min) 2.4.2.  
Final hold (min) 10.10.30.30.40.
I 1509.1472.1517.1529.1505.
ReferenceBertes, Freije, et al., 2005Bezic, Skocibusic, et al., 2005de la Fuente, Martinez-Castro, et al., 2005Joichi, Yomogida, et al., 2005Lee, Umano, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxSupelcowax-10PEG-20MBP-20Innowax FSC
Column length (m) 60.30.30.50.60.
Carrier gas Nitrogen   Helium
Substrate      
Column diameter (mm) 0.320.250.250.220.25
Phase thickness (μm) 0.500.25 0.25 
Tstart (C) 35.40.60.60.60.
Tend (C) 235.220.180.220.220.
Heat rate (K/min) 2.3.3.2.4.
Initial hold (min) 4.5.10. 10.
Final hold (min) 30.10.30.20. 
I 1545.1495.1517.1508.1532.
ReferenceQian and Wang, 2005Vichi, Riu-Aumatell, et al., 2005Yao, Guo, et al., 2005Blanc, Muselli, et al., 2004Lourens, Reddy, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase NB-20MSW-10DB-WaxDB-WaxHP-Innowax
Column length (m) 50.50.60.60.50.
Carrier gas HeHe NitrogenHe
Substrate      
Column diameter (mm) 0.20.200.250.250.2
Phase thickness (μm) 0.250.250.250.250.2
Tstart (C) 50.50.70.70.45.
Tend (C) 250.230.230.230.190.
Heat rate (K/min) 2.2.2.2.4.
Initial hold (min)   2.2.2.
Final hold (min)   20. 50.
I 1513.1500.1540.1540.1536.
ReferenceRaal, Arak, et al., 2004Raal, Paaver, et al., 2004Sawamura, Son, et al., 2004Sawamura, Sou, et al., 2004Soria, Gonzalez, et al., 2004
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10CP-Wax 52CBSW-10InnowaxCarbowax 20M
Column length (m) 30.60.50.60.25.
Carrier gas HeHeHeHeN2
Substrate      
Column diameter (mm) 0.250.250.200.250.25
Phase thickness (μm) 0.250.250.25 0.25
Tstart (C) 60.40.50.60.50.
Tend (C) 240.220.250.220.250.
Heat rate (K/min) 4.3.2.4.4.
Initial hold (min)    10. 
Final hold (min)    10.10.
I 1530.1516.1511.1532.1518.
ReferenceCabanillas, Lopez, et al., 2003Mau, Lai, et al., 2003Raal, Arak, et al., 2003Suleimenov, Atazharova, et al., 2003Zrira, Elamrani, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10Carbowax 20MDB-WaxCarbowax 20MPEG-20M
Column length (m) 30.30.60.30.50.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.2
Phase thickness (μm) 0.250.3250.250.25 
Tstart (C) 40.50.45.50.70.
Tend (C) 210.215.240.215.220.
Heat rate (K/min) 2.4.3.4.2.
Initial hold (min) 2.    
Final hold (min) 33.20.   
I 1486.1518.1518.1518.1511.
ReferenceKabouss, Charrouf, et al., 2002Kasali, Winterhalter, et al., 2002Christoph, 2001Kasali, Oyedeji, et al., 2001Orav and Kann, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Supelcowax-10DB-WaxCW 20MHP Innowax FSPInnowax
Column length (m) 60.60.25.60.60.
Carrier gas HeHeHydrogenHeHe
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.40.50.60.60.
Tend (C) 280.200.220.220.220.
Heat rate (K/min) 4.2.3.  
Initial hold (min)  2.1.10.10.
Final hold (min)   10.10. 
I 1537.1510.1488.1532.1532.
ReferenceKorány, Mednyánszky, et al., 2000Umano, Hagi, et al., 2000Bicchi, Binello, et al., 1999Kaya, Baser, et al., 1999Kaya, Baser, et al., 1999, 2
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxHP-20MDB-WaxSupelcowax-10CBP-20
Column length (m) 60.25.60.30.25.
Carrier gas HeHeliumN2He 
Substrate      
Column diameter (mm) 0.250.20 0.250.25
Phase thickness (μm) 0.250.250.25  
Tstart (C) 60.60.60.60.35.
Tend (C) 240.200.220.240.200.
Heat rate (K/min) 4.3.5.4.5.
Initial hold (min)  4.  5.
Final hold (min)      
I 1526.1534.1543.1516.1507.
ReferenceNgassoum, Yonkeu, et al., 1999Prikhod'ko, Klyuev, et al., 1999Weyerstahl, Marschall, et al., 1999Lamarque, Maestri, et al., 1998Quiroz A. and Niemeyer H.M., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-Innowax FSCDB-WaxPEG-20MDB-WaxTC-Wax
Column length (m) 60.60.50.60.60.
Carrier gas HeH2HeHe 
Substrate      
Column diameter (mm) 0.250.320.250.320.25
Phase thickness (μm) 0.250.25 0.50 
Tstart (C) 60.60.70.50.80.
Tend (C) 220.220.250.250.240.
Heat rate (K/min) 4.3.2.8.3.
Initial hold (min) 10.  1.5.
Final hold (min) 10.  6. 
I 1532.1528.1511.1525.1525.
ReferenceTümen, Baser, et al., 1998Werkhoff, Güntert, et al., 1998Orav, Kailas, et al., 1996Sagrero-Nieves and Bartley, 1996Shuichi, Masazumi, et al., 1996
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-WaxPEG-20MSupelcowax-10Supelcowax-10DB-Wax
Column length (m) 30.60.  60.
Carrier gas HydrogenHe  He
Substrate      
Column diameter (mm) 0.320.32  0.25
Phase thickness (μm) 0.500.25  0.25
Tstart (C) 30.70.40.40.50.
Tend (C) 190.180.210.210.230.
Heat rate (K/min) 3.2.2.2.2.
Initial hold (min) 6.7.2.2.4.
Final hold (min)   120.120. 
I 1529.1524.1515.1515.1511.
ReferenceYoung, Gilbert, et al., 1996Orav, Kuningas, et al., 1995Collin, Deslauriers, et al., 1993Collin, Deslauriers, et al., 1993Shimoda, Shiratsuchi, et al., 1993
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase Carbowax 20MDB-WaxDB-WaxCarbowax 20MCarbowax 20M
Column length (m) 45.30.30.150.100.
Carrier gas Hydrogen H2  
Substrate      
Column diameter (mm) 0.320.320.250.640.25
Phase thickness (μm) 1.0 0.25  
Tstart (C) 60.70.50.50.70.
Tend (C) 200.200.250.170.170.
Heat rate (K/min) 2.4.5.1.1.
Initial hold (min) 5.2. 30. 
Final hold (min)      
I 1497.1535.1507.1490.1537.
ReferenceKollmannsberger, Nitz, et al., 1992Wyllie, Brophy, et al., 1990Perry, Baxter, et al., 1986Buttery and Kamm, 1980Shibamoto and Jennings, 1977
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type Capillary
Active phase Carbowax 20M
Column length (m) 100.
Carrier gas  
Substrate  
Column diameter (mm) 0.25
Phase thickness (μm)  
Tstart (C) 70.
Tend (C) 170.
Heat rate (K/min) 1.
Initial hold (min)  
Final hold (min)  
I 1539.
ReferenceShibamoto and Jennings, 1977
Comment MSDC-RI

References

Go To: Top, Normal alkane RI, polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Feng, Zhuang, et al., 2011
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Tsai, Huang, et al., 2011
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Mishra, Chaudhary, et al., 2010
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Neves, Rosa, et al., 2010
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Museli, Pau, et al., 2009
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Soria, Sanz, et al., 2008
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Cheraif, Ben Jannet, et al., 2007
Cheraif, I.; Ben Jannet, H.; Hammami, M.; Khouja, M.L.; Mighri, Z., Chemical composition and antimicrobial activity of essential oils of Cupressus arizonica Greene, Biochem. Syst. Ecol., 2007, 35, 12, 813-820, https://doi.org/10.1016/j.bse.2007.05.009 . [all data]

Chen, Chyau, et al., 2007
Chen, C.-C.; Chyau, C.-C.; Hseu, TY.-H., Production of a COX-2 inhibitor, 2,4,5-trimethoxybenzaldehyde, with submerged cultured Antrodia camphorata, Lett. Appl. Microbiol., 2007, 44, 4, 387-392, https://doi.org/10.1111/j.1472-765X.2006.02087.x . [all data]

Ferhat, Meklati, et al., 2007
Ferhat, M.A.; Meklati, B.Y.; Chemat, F., Comparison of different isolation methods of essential oil from Citrus fruits: cold pressing, hydrodistillation and microwave dry distillation, Flavour Fragr. J., 2007, 22, 6, 494-504, https://doi.org/10.1002/ffj.1829 . [all data]

Hymete, Rohloff, et al., 2007
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Jerkovic, Mastelic, et al., 2007
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Kurose, Okamura, et al., 2007
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Pinto, Salgueiro, et al., 2007
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Raal, Orav, et al., 2007
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Abdelwahed, Hayder, et al., 2006
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Cavaleiro, Pinto, et al., 2006
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Kitchlu, Bakshi, et al., 2006
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Marzouk, Mansour, et al., 2006
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Marzouk, Neffati, et al., 2006
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Wong, Sivasothy, et al., 2006
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Bendimerad and Bendiab, 2005
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Bertes, Freije, et al., 2005
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Bezic, Skocibusic, et al., 2005
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de la Fuente, Martinez-Castro, et al., 2005
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Joichi, Yomogida, et al., 2005
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Lee, Umano, et al., 2005
Lee, S.-J.; Umano, K.; Shibamoto, T.; Lee, K.-G., Identification of volatile components in basil (Ocimum basilicum L.) and thyme leaves (Thymus vulgaris L.) and their antioxidant properties, Food Chem., 2005, 91, 1, 131-137, https://doi.org/10.1016/j.foodchem.2004.05.056 . [all data]

Qian and Wang, 2005
Qian, M.C.; Wang, Y., Seasonal Variations of Volatile Composition and Odor Activity Value of Marion (Rubus spp. hyb) and Thornless Evergreen (R.laciniatus L.) Blackberries, J. Food. Sci., 2005, 70, 1, c13-c20, https://doi.org/10.1111/j.1365-2621.2005.tb09013.x . [all data]

Vichi, Riu-Aumatell, et al., 2005
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Notes

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