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Phosgene

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - J.E. Bartmess
M - M. M. Meot-Ner (Mautner) and S. G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Phosgene = (Chlorine anion bullet Phosgene)

By formula: Cl- + CCl2O = (Cl- bullet CCl2O)

QuantityValueUnitsMethodReferenceComment
Deltar52.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
QuantityValueUnitsMethodReferenceComment
Deltar84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
QuantityValueUnitsMethodReferenceComment
Deltar27. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]


Notes

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