1-Butanol

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Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

ΔcH°liquid (kJ/mol) Method Reference Comment
-2676.18 ± 0.24CcbMosselman and Dekker, 1975Corresponding ΔfHºliquid = -327.01 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2640. ± 120.CcbDelafontaine, Sabbah, et al., 1973Δ U value; Corresponding ΔfHºliquid = -367. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2675.61 ± 0.45CcbGundry, Harrop, et al., 1969Corresponding ΔfHºliquid = -327.58 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2676.01 ± 0.24CcbMosselman and Dekker, 1969Corresponding ΔfHºliquid = -327.18 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2677.4 ± 0.63CcbChao and Rossini, 1965see Rossini, 1934; Corresponding ΔfHºliquid = -325.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2674.9 ± 0.84CcbSkinner and Snelson, 1960Corresponding ΔfHºliquid = -328.3 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2670.4 ± 0.42CcbTjebbes, 1960Corresponding ΔfHºliquid = -332.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2670.44CcbVerkade and Coops, 1928See Verkade and Coops, 1927 , Corrected for 298 and 1 atm.; Corresponding ΔfHºliquid = -332.75 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2676.0CcbParks, 1925Corresponding ΔfHºliquid = -327.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
-2670.77CcbRichards and Davis, 1920At 291 K; Corresponding ΔfHºliquid = -332.42 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

References

Go To: Top, Enthalpy of combustion of liquid at standard conditions (nominally 298.15 K, 1 atm.), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mosselman and Dekker, 1975
Mosselman, C.; Dekker, H., Enthalpies of formation of n-alkan-1-ols, J. Chem. Soc. Faraday Trans. 1, 1975, 417-424. [all data]

Delafontaine, Sabbah, et al., 1973
Delafontaine, J.; Sabbah, R.; Laffitte, M., Mesures microcalorimetriques des enthalpies de reference de formation (a l'etat condense) de composes volatils - mise au point de la technique, Z. Phys. Chem. (Neue Folge), 1973, 84, 157-172. [all data]

Gundry, Harrop, et al., 1969
Gundry, H.A.; Harrop, D.; Head, A.J.; Lewis, G.B., Thermodynamic properties of organic oxygen compounds. 21. Enthalpies of combustion of benzoic acid, pentan-1-ol, octan-1-ol, and hexadecan-1-ol, J. Chem. Thermodyn., 1969, 1, 321-332. [all data]

Mosselman and Dekker, 1969
Mosselman, C.; Dekker, H., A new method for handling volatile and hygroscopic substances in bomb calorimetry enthalpy of formation of liquid butanol, Recl. Trav. Chim. Pays-Bas, 1969, 257-261. [all data]

Chao and Rossini, 1965
Chao, J.; Rossini, F.D., Heats of combustion, formation, and isomerization of nineteen alkanols, J. Chem. Eng. Data, 1965, 10, 374-379. [all data]

Rossini, 1934
Rossini, F.D., Heats of combustion and of formation of the normal aliphatic alcohols in the gaseous and liquid states, and the energies of their atomic linkages, J. Res. NBS, 1934, 13, 189-197. [all data]

Skinner and Snelson, 1960
Skinner, H.A.; Snelson, A., The heats of combustion of the four isomeric butyl alcohols, Trans. Faraday Soc., 1960, 56, 1776-1783. [all data]

Tjebbes, 1960
Tjebbes, J., Heats of combustion of butannal and some related compounds, Acta Chem. Scand., 1960, 14, 180-188. [all data]

Verkade and Coops, 1928
Verkade, P.E.; Coops, J., Jr., Further remarks on the method proposed by swietoslawski for the correction of the older thermochemical data, Recl. Trav. Chim. Pays-Bas, 1928, 47, 701-708. [all data]

Verkade and Coops, 1927
Verkade, P.E.; Coops, J., Jr., Calorimetric researches XIV. Heats of combustion of successive members of homologous series: the normal primary aliphatic alcohols, Recl. Trav. Chim. Pays-Bas, 1927, 46, 903-917. [all data]

Parks, 1925
Parks, G.S., Thermal data on organic compounds I. The heat capacities and free energies of methyl, ethyl and normal-butyl alcohols, J. Am. Chem. Soc., 1925, 47, 338-345. [all data]

Richards and Davis, 1920
Richards, T.W.; Davis, H.S., The heats of combustion of benzene, toluene, aliphatic alcohols, cyclohexanol, and other carbon compounds, J. Am. Chem. Soc., 1920, 42, 1599-1617. [all data]

Notes

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