Vanillin, TMS derivative
- Formula: C11H16O3Si
- Molecular weight: 224.3284
- IUPAC Standard InChI: InChI=1S/C11H16O3Si/c1-13-11-7-9(8-12)5-6-10(11)14-15(2,3)4/h5-8H,1-4H3
- IUPAC Standard InChIKey: PTXKWJXZIMEWED-UHFFFAOYSA-N
- CAS Registry Number: 6689-43-6
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Benzaldehyde, 3-methoxy-4-[(trimethylsilyl)oxy]-; m-Anisaldehyde, 4-(trimethylsiloxy)-; Trimethylsilyl vanillin; Vanillin, TMS; Vanillin, trimethylsilyl ether; 3-Methoxy-4-[(trimethylsilyl)oxy]benzaldehyde; Vanilline, TMS
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | SE-30 | 1494. | Lhuguenot, Maume, et al., 1971 | N2, Gas Chrom P (120-140 mesh), 1. K/min; Column length: 3. m; Tstart: 100. C; Tend: 180. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1544.9 | Tret'yakov, 2008 | 30. m/0.25 mm/0.25 μm, He; Program: Multi-step temperature program; T(initial)=60C; T(final)=270C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1529. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium, 3. K/min, 300. C @ 30. min; Tstart: 50. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1530. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lhuguenot, Maume, et al., 1971
Lhuguenot, J.C.; Maume, B.F.; Baron, C.,
Gas Chromatographic and Mass Spectrometric Study of Vanillin Related Compounds,
Chromatographia, 1971, 4, 5, 204-208, https://doi.org/10.1007/BF02281053
. [all data]
Tret'yakov, 2008
Tret'yakov, K.V.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2008. [all data]
Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L.,
Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack,
Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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