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Vinyl bromide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - S.G. Lias

Data compiled as indicated in comments:
LBLHLM - S.G. Lias, J.E. Bartmess, J.F. Liebman, J.L. Holmes, R.D. Levin, and W.G. Mallard
LLK - S.G. Lias, R.D. Levin, and S.A. Kafafi
RDSH - H.M. Rosenstock, K. Draxl, B.W. Steiner, and J.T. Herron

QuantityValueUnitsMethodReferenceComment
IE (evaluated)9.82 ± 0.03eVN/AN/AL

Ionization energy determinations

IE (eV)MethodReferenceComment
9.90 ± 0.01SSchander and Russell, 1976LLK
9.80PELohr, Jochims, et al., 1975LLK
9.83PEMines and Thompson, 1973LLK
9.80 ± 0.02PEChadwick, Frost, et al., 1972LLK
9.82 ± 0.02PIMomigny, 1963RDSH
9.80 ± 0.01PIWatanabe, Nakayama, et al., 1962RDSH
9.80PIBralsford, Harris, et al., 1960RDSH
9.9PECambi, Ciullo, et al., 1983Vertical value; LBLHLM
9.9PEVon Niessen, Asbrink, et al., 1982Vertical value; LBLHLM
9.87PEWittel and Bock, 1974Vertical value; LLK

Appearance energy determinations

IonAE (eV)Other ProductsMethodReferenceComment
HBr+18.2 ± 0.1?PILohr, Jochims, et al., 1975LLK
C2H2+12.5 ± 0.2HBrPILohr, Jochims, et al., 1975LLK
C2H3+11.92BrDERMiller and Baer, 1984T = 0K; LBLHLM
C2H3+11.9 ± 0.1BrPILohr, Jochims, et al., 1975LLK
C2H3+12.01 ± 0.13BrEIFinney and Harrison, 1972LLK
C2H3+11.9BrEILossing, 1971LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schander and Russell, 1976
Schander, J.; Russell, B.R., Vacuum ultraviolet spectra of bromoethylene and dibromoethylenes, J. Am. Chem. Soc., 1976, 98, 6900. [all data]

Lohr, Jochims, et al., 1975
Lohr, W.; Jochims, H.-W.; Baumgartel, H., Photoreaktionen kleiner organischer Molekule IV Absorptionsspektren, Photoionen- und Resonanz- photoelektronenspektren von Vinylbromid, Ber. Bunsen-Ges. Phys. Chem., 1975, 79, 901. [all data]

Mines and Thompson, 1973
Mines, G.W.; Thompson, H.W., Photoelectron spectra of vinyl and allyl halides, Spectrochim. Acta Part A, 1973, 29, 1377. [all data]

Chadwick, Frost, et al., 1972
Chadwick, D.; Frost, D.C.; Katrib, A.; McDowell, C.A.; McLean, R.A.N., Photoelectron spectra of some bromoethylenes and 2-bromopropene, Can. J. Chem., 1972, 50, 2642. [all data]

Momigny, 1963
Momigny, J., Ionization potentials and the structures of the photo-ionization yield curves of ethylene and its halogeno derivatives, Nature, 1963, 199, 1179. [all data]

Watanabe, Nakayama, et al., 1962
Watanabe, K.; Nakayama, T.; Mottl, J., Ionization potentials of some molecules, J. Quant. Spectry. Radiative Transfer, 1962, 2, 369. [all data]

Bralsford, Harris, et al., 1960
Bralsford, R.; Harris, P.V.; Price, W.C., The effect of fluorine on the electronic spectra and ionization potentials of molecules, Proc. Roy. Soc. (London), 1960, A258, 459. [all data]

Cambi, Ciullo, et al., 1983
Cambi, R.; Ciullo, G.; Sgamellotti, A.; Tarantelli, F.; Fantoni, R.; Giardini-Guidoni, A.; McCarthy, I.E.; di Martino, V., An (e,2e) spectroscopic investigation and a Green's Function Study of the ionization of chloro- and bromoethylene, Chem. Phys. Lett., 1983, 101, 477. [all data]

Von Niessen, Asbrink, et al., 1982
Von Niessen, W.; Asbrink, L.; Bieri, G., 30.4 nm He(II) Photoelectron spectra of organic molecules. Part VI. Halogeno-compounds (C,H,X: X = Cl, Br, I), J. Electron Spectrosc. Relat. Phenom., 1982, 26, 173. [all data]

Wittel and Bock, 1974
Wittel, K.; Bock, H., Photoelektronenspekten und molekuleigenschaften. XXVII. Chlor- und bromathylene- beispiele fur anderungen in «pi»- und «sigma»-Systemen, Chem. Ber., 1974, 107, 317. [all data]

Miller and Baer, 1984
Miller, B.E.; Baer, T., Kinetic energy release distribution in the fragmentation of energy-selected vinyl and ethyl bromide ions, Chem. Phys., 1984, 85, 39. [all data]

Finney and Harrison, 1972
Finney, C.D.; Harrison, A.G., A third-derivative method for determining electron-impact onset potentials, Int. J. Mass Spectrom. Ion Phys., 1972, 9, 221. [all data]

Lossing, 1971
Lossing, F.P., Free radicals by mass spectrometry. XLIII. Ionization potentials and ionic heats of formation for vinyl, allyl, and benzyl radicals, Can. J. Chem., 1971, 49, 357. [all data]


Notes

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