Cyclohexane, chloro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil416. ± 1.KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus230.15KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.3 K; TRC
Tfus230.1KN/ATimmermans, 1952Uncertainty assigned by TRC = 0.3 K; TRC
Tfus228.8KN/ACrowe and Smyth, 1951Crystal phase 1 phase; Uncertainty assigned by TRC = 0.3 K; TRC
Tfus226.KN/AWhite and Bishop, 1940Crystal phase 1 phase; Uncertainty assigned by TRC = 3. K; TRC
Tfus230.00KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 1.5 K; by cryoscopic; TRC
Quantity Value Units Method Reference Comment
Ttriple229.34KN/ADiky, Kabo, et al., 1994Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Δvap42. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
39.3365.AStephenson and Malanowski, 1987Based on data from 350. - 416. K. See also Andreevskii, Brazhnikov, et al., 1969.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
1.67228.7DSCSingh and Murthy, 2008AC
2.04229.3ACDiky, Kabo, et al., 1994, 2Based on data from 5. - 304. K.; AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
0.42120.Kozyro, Kabo, et al., 1992CAL
36.35220.4
8.91229.3

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Timmermans and Hennaut-Roland, 1955
Timmermans, J.; Hennaut-Roland, M., Work of the International Bureau of Physical-Chemical Standards. IX. The Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1955, 52, 223. [all data]

Timmermans, 1952
Timmermans, J., Freezing points of organic compounds. VVI New determinations., Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]

Crowe and Smyth, 1951
Crowe, R.W.; Smyth, C.P., J. Am. Chem. Soc., 1951, 73, 5406. [all data]

White and Bishop, 1940
White, A.H.; Bishop, W.S., Dielectric Evidence of Molecular Rotation in the Crystals of Certain Non-aromatic Compounds, J. Am. Chem. Soc., 1940, 62, 8-16. [all data]

Van de Vloed, 1939
Van de Vloed, A., Bull. Soc. Chim. Belg., 1939, 48, 229. [all data]

Diky, Kabo, et al., 1994
Diky, V.V.; Kabo, G.J.; Kozyro, A.A.; Krasulin, A.P.; Sevruk, V.M., Thermodynamic properties of crystalline and liquid chlorocyclohexane and inversion of ring, J. Chem. Thermodyn., 1994, 26, 9, 1001, https://doi.org/10.1006/jcht.1994.1117 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Andreevskii, Brazhnikov, et al., 1969
Andreevskii, D.N.; Brazhnikov, M.M.; Il'inchik, V.N., Vestn. Beloruss. Univ., 1969, 2, 1, 3. [all data]

Singh and Murthy, 2008
Singh, L.P.; Murthy, S.S.N., Dielectric and Calorimetric Study of Orientationally Disordered Phases in Two Unusual Two-Component Systems, J. Phys. Chem. B, 2008, 112, 9, 2606-2615, https://doi.org/10.1021/jp077663o . [all data]

Diky, Kabo, et al., 1994, 2
Diky, V.V.; Kabo, G.J.; Kozyro, A.A.; Krasulin, A.P.; Sevruk, V.M., Thermodynamic properties of crystalline and liquid chlorocyclohexane and inversion of ring, J. Chem. Thermodyn., 1994, 26, 1001-1013. [all data]

Kozyro, Kabo, et al., 1992
Kozyro, A.A.; Kabo, G.J.; Krouk, V.S.; Sheiman, M.S.; Yursha, I.A.; Simirsky, V.V.; Krasulin, A.P.; Sevruk, V.M.; Gogolinsky, V.I., Thermodynamic properties of cyclohexanone oxime, J. Chem. Thermodyn., 1992, 24, 8, 883, https://doi.org/10.1016/S0021-9614(05)80233-2 . [all data]


Notes

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