Tropinone
- Formula: C8H13NO
- Molecular weight: 139.1949
- IUPAC Standard InChI: InChI=1S/C8H13NO/c1-9-6-2-3-7(9)5-8(10)4-6/h6-7H,2-5H2,1H3
- IUPAC Standard InChIKey: QQXLDOJGLXJCSE-UHFFFAOYSA-N
- CAS Registry Number: 532-24-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 8-Azabicyclo[3.2.1]octan-3-one, 8-methyl-; 1αH,5αH-Tropan-3-one; Tropanon; Tropanone; Tropinon; 3-Tropanone; 3-Tropinone; Tropionone; 8-Methyl-8-azabicyclo[3.2.1]octan-3-one; 1Ah,5ah-tropan-3-one; N-Methyl-8-azabicyclo[3.2.1]octan-3-one; NSC 118012; 1alphaH,5alphaH-Tropan-3-one; 25866-00-6; 35193-79-4; Tropan-3-one
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1150. | Jenett-Siems, Weigl, et al., 2005 | He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 70. C; Tend: 300. C |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5MS | 1196. | Humam, Munoz, et al., 2007 | 30. m/0.25 mm/0.25 μm, 70. C @ 1. min, 5. K/min, 285. C @ 15. min |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5MS | 1201.8 | Andriamaharavo, 2014 | 30. m/0.25 mm/0.25 μm, He; Program: 60C (1 min) => 5 C/min => 210C => 10 C/min => 280C (15 min) |
| Capillary | HP-5MS | 1198. | Humam, Munoz, et al., 2007 | 30. m/0.25 mm/0.25 μm; Program: not specified |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-1 | 1153. | Ei-Shazly and Wink M., 2008 | 15. m/0.317 mm/0.25 μm, He; Program: 100 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 300 0C (5 min) |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Jenett-Siems, Weigl, et al., 2005
Jenett-Siems, K.; Weigl, R.; Böhm, A.; Mann, P.; Tofern-Reblin, B.; Ott, S.C.; Ghomian, A.; Kaloga, M.; Siems, K.; Witte, L.; Hilker, M.; Müller, F.; Eich, E.,
Chemotaxonomy of the pantropical genus Merremia (Convolvulaceae) based on the distribution of tropane alkaloids,
Phytochemistry, 2005, 66, 12, 1448-1464, https://doi.org/10.1016/j.phytochem.2005.04.027
. [all data]
Humam, Munoz, et al., 2007
Humam, M.; Munoz, O.; Christen, P.; Hostettmann, K.,
Tropane alkaloids of the aerial part of Schizanthus tricolor,
Nat. Prod. Commun., 2007, 2, 7, 743-747. [all data]
Andriamaharavo, 2014
Andriamaharavo, N.R.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]
Ei-Shazly and Wink M., 2008
Ei-Shazly, A.; Wink M.,
Tropane and pyrrolidine alkaloids from Convolvulus lanatus Vahl,
Z. Naturforsch. C:, 2008, 63, 5-6, 321-325. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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