Propane, 3-chloro-1,1,1-trifluoro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil319.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Ttriple179.32KN/AKolesov, Vorob'ev, et al., 1974Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple179.40KN/AKolesov and Vorob'ev, 1972Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
29.9306.AStephenson and Malanowski, 1987Based on data from 297. - 315. K.; AC
33.7316.N/AVarushchenko and Druzhinina, 1972Based on data from 301. - 341. K.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
5.31179.4Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
26.44169.8Domalski and Hearing, 1996CAL
28.2179.3

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
-2.531116.0crystaline, IIIcrystaline, IIKolesov, Vorob'ev, et al., 1974, 2Maximum temperature of metastable phase. H obtained from total heat 115 to 137 K, calculated to 116 K. Not reversible.; DH
4.489169.8crystaline, IIcrystaline, IKolesov, Vorob'ev, et al., 1974, 2DH
5.050179.32crystaline, IliquidKolesov, Vorob'ev, et al., 1974, 2DH
-2.5330116.0crystaline, IIIcrystaline, IIKolesov and Vorob'ev, 1972, 2Metastable crystal transition. Non-equilibrium.; DH
4.489169.8crystaline, IIcrystaline, IKolesov and Vorob'ev, 1972, 2DH
5.314179.40crystaline, IliquidKolesov and Vorob'ev, 1972, 2DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
26.44169.8crystaline, IIcrystaline, IKolesov, Vorob'ev, et al., 1974, 2DH
28.16179.32crystaline, IliquidKolesov, Vorob'ev, et al., 1974, 2DH
26.44169.8crystaline, IIcrystaline, IKolesov and Vorob'ev, 1972, 2DH
29.62179.40crystaline, IliquidKolesov and Vorob'ev, 1972, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Kolesov, Vorob'ev, et al., 1974
Kolesov, V.P.; Vorob'ev, V.N.; Sarzhina, E.A.; Pentin, Y.A.; Timoshenkova, Yu.D., Heat capacity from 12 to 300 K, phase transitions, and thermodynamic functions of 1,1,1-trifluoro-3-chloropropane and 1,1,1,3-tetrachloropropane, J. Chem. Thermodyn., 1974, 6, 613-28. [all data]

Kolesov and Vorob'ev, 1972
Kolesov, V.P.; Vorob'ev, V.N., Specific heat in the interval 12-300 K and phase changes for some chlorinated 1,1,1-trifluoropropanes, Dokl. Akad. Nauk SSSR, 1972, 203, 116-9. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Varushchenko and Druzhinina, 1972
Varushchenko, R.M.; Druzhinina, A.I., Zh. Fiz. Khim., 1972, 46, 5, 1312. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Kolesov, Vorob'ev, et al., 1974, 2
Kolesov, V.P.; Vorob'ev, V.N.; Sarzhina, E.A.; Pentin, Yu.A.; Timoshenkova, Yu.D., Heat capacity from 12 to 300 K, phase transitions, and thermodynamic functions of 1,1,1-trifluoro-3-chloropropane and 1,1,1,3-tetrachloropropane, J. Chem. Thermodynam., 1974, 6, 613-628. [all data]

Kolesov and Vorob'ev, 1972, 2
Kolesov, V.P.; Vorob'ev, V.N., Specific heat in the interval 12-300K and phase changes for some chlorinated 1,1,1-trifluoropropanes, Dokl. Akad. Nauk, 1972, SSSR 203, 116-119. [all data]


Notes

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