trans-1-(Phenylthio)-2-butene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

trans-1-(Phenylthio)-2-butene = (E) 1-Phenylthio-1-butene

By formula: C10H12S = C10H12S

Quantity Value Units Method Reference Comment
Δr0.8 ± 0.1kJ/molEqkKimmelma, 1988liquid phase; solvent: DMSO; NMR

trans-1-(Phenylthio)-2-butene = Benzene, (2-butenylthio)-, (Z)-

By formula: C10H12S = C10H12S

Quantity Value Units Method Reference Comment
Δr3.3 ± 0.3kJ/molEqkKimmelma, 1987liquid phase; solvent: DMSO

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kimmelma, 1988
Kimmelma, R., Structure-stability relationships in vinyl sulfides. III. Stabilization caused by different alkylthio and phenylthio groups attached to an olefinic double bond, Acta Chem. Scand., 1988, 42, 550-555. [all data]

Kimmelma, 1987
Kimmelma, R., The stabilization due to the methyl group in RSCH2CH=CHCH3, Acta Chem. Scand., 1987, 41, 344-347. [all data]


Notes

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