2-Chloro-2,4-dimethylpentane

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

1-Pentene, 2,4-dimethyl- + Hydrogen chloride = 2-Chloro-2,4-dimethylpentane

By formula: C7H14 + HCl = C7H15Cl

Quantity Value Units Method Reference Comment
Δr-54.0 ± 2.2kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

2-Pentene, 2,4-dimethyl- + Hydrogen chloride = 2-Chloro-2,4-dimethylpentane

By formula: C7H14 + HCl = C7H15Cl

Quantity Value Units Method Reference Comment
Δr-47.6 ± 1.5kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnett and Pienta, 1980
Arnett, E.M.; Pienta, N.J., Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions, J. Am. Chem. Soc., 1980, 102, 3329-3334. [all data]


Notes

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