2-Chloro-1,1,2-trifluoroethyl ethyl ether

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil362.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tc524.4KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Δvap37.63kJ/molN/AMajer and Svoboda, 1985 
Δvap37.5 ± 0.1kJ/molCUchytilová, Majer, et al., 1984AC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
355.0.840PCR Inc., 1990BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
32.57362.N/AMajer and Svoboda, 1985 
36.5 ± 0.1313.CUchytilová, Majer, et al., 1984AC
35.3 ± 0.1328.CUchytilová, Majer, et al., 1984AC
34.2 ± 0.1343.CUchytilová, Majer, et al., 1984AC
32.9 ± 0.1358.CUchytilová, Majer, et al., 1984AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
298. - 368.58.420.3138524.4Majer and Svoboda, 1985 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Uchytilová, Majer, et al., 1984
Uchytilová, V.; Majer, V.; Svoboda, V.; Hemer, I., Enthalpies of vaporization and cohesive energies of 2-chloro-1,1,2-trifluoroethyl ethyl ether, 2-chloro-1,1,2-trifluoroethyl propyl ether, 2-chloro-1,1,2-trifluoroethyl chloromethyl ether, and 2-chloro-1,1,2-trifluoroethyl difluoromethyl ether, The Journal of Chemical Thermodynamics, 1984, 16, 5, 475-479, https://doi.org/10.1016/0021-9614(84)90205-2 . [all data]

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]


Notes

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