CH2N(CH3)2
- Formula: C3H8N
- Molecular weight: 58.1023
- IUPAC Standard InChI: InChI=1S/C3H8N/c1-4(2)3/h1H2,2-3H3
- IUPAC Standard InChIKey: VMWJCFLUSKZZDX-UHFFFAOYSA-N
- CAS Registry Number: 30208-47-0
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
View reactions leading to C3H8N+ (ion structure unspecified)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°(+) ion | 661. | kJ/mol | N/A | N/A |
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| <-0.118 ± 0.066 | D-EA | MacKay and Bohme, 1978 | Computations put dHacid ca. 412 kcal/mol; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 5.7 | DER | Burkey, Castelhano, et al., 1983 | LBLHLM |
| 5.35 | PI | Loguinov, Takhistov, et al., 1981 | LLK |
| 5.7 | DER | Griller and Lossing, 1981 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
MacKay and Bohme, 1978
MacKay, G.I.; Bohme, D.K.,
Proton-Transfer Reactions in Nitromethane at 297K,
Int. J. Mass Spectrom. Ion Phys., 1978, 26, 4, 327, https://doi.org/10.1016/0020-7381(78)80052-7
. [all data]
Burkey, Castelhano, et al., 1983
Burkey, T.J.; Castelhano, A.L.; Griller, D.; Lossing, F.P.,
Heats of formation and ionization potentials of some α-aminoalkyl radicals,
J. Am. Chem. Soc., 1983, 105, 4701. [all data]
Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P.,
Photoionization studies of substituted trimethylamines,
Org. Mass Spectrom., 1981, 16, 239. [all data]
Griller and Lossing, 1981
Griller, D.; Lossing, F.P.,
On the thermochemistry of α-aminoalkyl radicals,
J. Am. Chem. Soc., 1981, 103, 1586. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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