Cyclotetramethylenetetranitramine

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid18.kcal/molCcbOrnellas, 1974E.J. Prosen unpublished result; ALS
Δfsolid24.5 ± 0.66kcal/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=21. kcal/mol; ALS
Δfsolid17.9kcal/molCcbHandrick, 1956Naval Ordnance Laboratory, 1951; ALS
Quantity Value Units Method Reference Comment
Δcsolid-674. ± 0.66kcal/molCcbKrien, Licht, et al., 1973Author's hf298_condensed=21. kcal/mol; ALS
Δcsolid-667.4kcal/molCcbHandrick, 1956Naval Ordnance Laboratory, 1951; ALS
Δcsolid-663.1kcal/molCcbHandrick, 1956Stegeman, G. Univ. of Pittsburg 1945; ALS
Δcsolid-656.9kcal/molCcbHandrick, 1956W. R. Tomlinson 1949; ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
69.36298.Yin, Ziru, et al., 1991T = 290 to 345 K. Cp value reported at 298 K is 0.980 J/kg*K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ornellas, 1974
Ornellas, D.L., The heat and products of detonation in a calorimeter of CNO, HNO, CHNF, CHNO, CHNOF, and CHNOSi explosives, Combust. Flame, 1974, 23, 37-46. [all data]

Krien, Licht, et al., 1973
Krien, G.; Licht, H.H.; Zierath, J., Thermochemical investigation of nitramines, Thermochim. Acta, 1973, 6, 465-472. [all data]

Handrick, 1956
Handrick, G.R., Report of the study of pure explosive compounds. Part IV. Calculation of heat of combustion of organic compounds from structural features and calculation of power of high explosives, Rpt. C-58247 for the Office of the Chief of Ordnance, contract DA-19-020-ORD-47 by the Arthur D. Little, Inc., Cambridge, MA, 1956, 467-573. [all data]

Yin, Ziru, et al., 1991
Yin, C.; Ziru, L.; Ganghe, W.; Chengyun, W., et al., Determination of heat capacity of explosives and related materials by DSC, Proc. Int. Pyrotech. Semin. 17th(Vol. 1), 1991, 515-521. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References