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Bicyclo[2.2.2]oct-2-ene-1-carboxylic acid


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: J.E. Bartmess

De-protonation reactions

C9H11O2- + Hydrogen cation = Bicyclo[2.2.2]oct-2-ene-1-carboxylic acid

By formula: C9H11O2- + H+ = C9H12O2

QuantityValueUnitsMethodReferenceComment
Deltar1432. ± 9.2kJ/molG+TSTaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale
QuantityValueUnitsMethodReferenceComment
Deltar1403. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase; value altered from reference due to change in acidity scale

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

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