vanadium nitride


Solid Phase Heat Capacity (Shomate Equation)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 3500.
A 10.50160
B 2.680560
C -0.156640
D 0.010580
E -0.194961
F -55.80500
G 19.72200
H -51.90019
ReferenceChase, 1998
Comment Data last reviewed in December, 1973
Temperature
(K)
Cp
(cal/mol*K)

(cal/mol*K)
-(G° - H°298.15)/T
(cal/mol*K)
H° - H°298.15
(kcal/mol)
298.9.098.908.91-0.00
300.9.138.968.910.01
400.10.3311.779.280.99
500.11.0214.1510.022.06
600.11.5116.2110.893.19
700.11.9118.0111.784.36
800.12.2519.6312.665.57
900.12.5521.0913.526.81
1000.12.8422.4314.348.08
1100.13.1123.6615.139.38
1200.13.3824.8115.8910.70
1300.13.6325.9016.6212.06
1400.13.8826.9117.3213.43
1500.14.1227.8817.9914.83
1600.14.3628.8018.6416.25
1700.14.5929.6819.2617.70
1800.14.8230.5219.8719.17
1900.15.0531.3220.4520.67
2000.15.2732.1021.0122.18
2100.15.4932.8521.5623.72
2200.15.7133.5822.0925.28
2300.15.9334.2822.6026.86
2400.16.1534.9623.1028.47
2500.16.3635.6323.5930.09
2600.16.5736.2724.0731.74
2700.16.7836.9024.5333.41
2800.16.9937.5224.9835.09
2900.17.1938.1225.4336.80
3000.17.4038.7025.8638.53
3100.17.6039.2826.2840.28
3200.17.8039.8426.7042.05
3300.18.0040.3927.1043.84
3400.18.2040.9327.5045.65
3500.18.4041.4627.8947.48

References

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Solid Phase Heat Capacity (Shomate Equation), References