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Chlorine atom

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

QuantityValueUnitsMethodReferenceComment
Deltafgas121.301 ± 0.008kJ/molReviewCox, Wagman, et al., 1984CODATA Review value
Deltafgas121.30kJ/molReviewChase, 1998Data last reviewed in June, 1982
QuantityValueUnitsMethodReferenceComment
gas,1 bar165.190 ± 0.004J/mol*KReviewCox, Wagman, et al., 1984CODATA Review value
gas,1 bar165.19J/mol*KReviewChase, 1998Data last reviewed in June, 1982

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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Temperature (K)298. - 600.600. - 6000.
A13.3829823.26597
B42.33999-1.555939
C-64.746560.346910
D32.99532-0.025961
E0.0633190.153212
F116.1491114.6604
G171.7038193.8882
H121.3021121.3021
ReferenceChase, 1998Chase, 1998
CommentData last reviewed in June, 1982Data last reviewed in June, 1982

References

Go To: Top, Gas phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A., CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, References