Sulfuric acid, 2TMS derivative
- Formula: C6H18O4SSi2
- Molecular weight: 242.441
- IUPAC Standard InChI: InChI=1S/C6H18O4SSi2/c1-12(2,3)9-11(7,8)10-13(4,5)6/h1-6H3
- IUPAC Standard InChIKey: KRUQDZRWZXUUAD-UHFFFAOYSA-N
- CAS Registry Number: 18306-29-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Bis(trimethylsilyl) sulfate; Sulfuric acid, bis(trimethylsilyl) ester; Silanol, trimethyl-, sulfate (2:1); Sulfuric acid, bis(trimethylsilyl)-; Sulfuric acid, TMS; bis(trimethylsilyl) sulphate
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Options:
Gas Chromatography
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-2 | 1171. | Tuchman, Bowers, et al., 1984 | 25. m/0.31 mm/0.52 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Packed | SE-30 | 1148. | Butts and Rainey, 1971 | 5. K/min; Tstart: 70. C; Tend: 150. C |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W.,
Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column,
J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198
. [all data]
Butts and Rainey, 1971
Butts, W.C.; Rainey, W.T., Jr.,
Gas Chromatography and Mass Spectrometry of the Trimethylsilyl Derivatives of Inorganic Anions,
Anal. Chem., 1971, 43, 4, 538-542, https://doi.org/10.1021/ac60299a004
. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.