Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Methanethiol, trimethylsilyl-


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - S.G. Lias and J.F. Liebman
LBLHLM - S.G. Lias, J.E. Bartmess, J.F. Liebman, J.L. Holmes, R.D. Levin, and W.G. Mallard

Ionization energy determinations

IE (eV)MethodReferenceComment
8.8PEErmakov, Kirichenko, et al., 1987LBLHLM
8.96 ± 0.05PEBlock, Yencha, et al., 1988Vertical value; LL
9.11PEErmakov, Kirichenko, et al., 1987Vertical value; LBLHLM

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ermakov, Kirichenko, et al., 1987
Ermakov, A.I.; Kirichenko, E.A.; Makrushin, N.A.; Viasova, N.N.; Maroshina, M.Y.; Voronkov, M.G., Electronic spectra and electronic structure of trialkoxysilylalkanethiols, J. Struct. Chem., 1987, 28, 46. [all data]

Block, Yencha, et al., 1988
Block, E.; Yencha, A.J.; Aslam, M.; Eswarakrishnan, V.; Luo, J.; Sano, A., Gas-phase determination of the geometric requirements of the silicon B-effect. Photoelectron and penning ionization electron spectroscopic study of silylthiiranes and -oxiranes. Synthesis and chemistry of trans-2,3-bis(trimethylsilyl)thiirane, J. Am. Chem. Soc., 1988, 110, 4748. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References