L-Histidine, N,1-bis(trimethylsilyl)-, trimethylsilyl ester

Formula: C₁₅H₃₃N₃O₂Si₃
Molecular weight: 371.6979
IUPAC Standard InChI: InChI=1S/C15H33N3O2Si3/c1-21(2,3)17-14(15(19)20-23(7,8)9)10-13-11-18(12-16-13)22(4,5)6/h11-12,14,17H,10H2,1-9H3/t14-/m0/s1
IUPAC Standard InChIKey: MEFLGORIMZDUEG-AWEZNQCLSA-N
CAS Registry Number: 17908-25-7
Chemical structure:
This structure is also available as a 2d Mol file
Stereoisomers:
- Histidine, N,N,O-3TMS
Other names: Histidine, N,1-bis-(trimethylsilyl)-, trimethylsilyl ester; N,N',o-Tris-(trimethylsilyl)histidine; Imidazole-4-alanine, N,1-bis(trimethylsilyl)-, trimethylsilyl ester, L-; Histidine, tri-TMS; HIS, tris-TMS; His, TMS; Histidine, TMS
Permanent link for this species. Use this link for bookmarking this species for future reference.
Information on this page:
Other data available:
- Mass spectrum (electron ionization)
Options:
- Switch to SI units

Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	SP-2100	150.	1916.60	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm
Capillary	SP-2100	210.	1921.05	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm
Capillary	SE-54	150.	1942.25	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm
Capillary	SE-54	190.	1941.81	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm

Column type	Active phase	I	Reference	Comment
Capillary	SP-2100	1920.38	Gajewski, Dizdaroglu, et al., 1982	He, 6. K/min; Column length: 12. m; Column diameter: 0.2 mm; T_start: 80. C; T_end: 250. C

Column type	Active phase	I	Reference	Comment
Capillary	SE-54	1947.08	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm; Program: 70C => 4C/min => 170C=8C/min => 250C

Column type	Active phase	Temperature (C)	I	Reference	Comment
Capillary	Carbowax 20M	200.	2293.85	Gajewski, Dizdaroglu, et al., 1982	He; Column length: 12. m; Column diameter: 0.2 mm

Column type	Active phase	I	Reference	Comment
Packed	OV-1	1914.	Butts, 1972	He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; T_start: 100. C; T_end: 325. C
Packed	OV-1	1914.	Butts, 1972	He, Chromosorb W HP (80-100 mesh), 10. K/min; Column length: 2. m; T_start: 100. C; T_end: 325. C

Go To: Top, Gas Chromatography, Notes

Gajewski, Dizdaroglu, et al., 1982
Gajewski, E.; Dizdaroglu, M.; Simic, M.G., Kovats' Indices of Trimethylsilylated Amino Acids on Fused-Silica Capillary Columns, J. Chromatogr., 1982, 249, 1, 41-55, https://doi.org/10.1016/S0021-9673(00)80231-9 . [all data]

Butts, 1972
Butts, W.C., Two-Column Gas Chromatography of Trimethylsilyl Derivatives of Biochemically Significant Compounds, Anal. Biochemistry, 1972, 46, 1, 187-199, https://doi.org/10.1016/0003-2697(72)90411-3 . [all data]

Go To: Top, Gas Chromatography, References

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
Customer support for NIST Standard Reference Data products.