Perhydrotriquinacene


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2Hydrogen + C10H12 = Perhydrotriquinacene

By formula: 2H2 + C10H12 = C10H16

Quantity Value Units Method Reference Comment
Δr-230. ± 2.kJ/molChydLiebman, Paquette, et al., 1986liquid phase; solvent: Hexane

3Hydrogen + 2a,4a,6a,6b-Tetrahydrocyclopenta[cd]pentalene = Perhydrotriquinacene

By formula: 3H2 + C10H10 = C10H16

Quantity Value Units Method Reference Comment
Δr-326. ± 2.kJ/molChydLiebman, Paquette, et al., 1986liquid phase; solvent: Hexane

Hydrogen + Tetrahydrotriquinacene = Perhydrotriquinacene

By formula: H2 + C10H14 = C10H16

Quantity Value Units Method Reference Comment
Δr-115. ± 1.kJ/molChydLiebman, Paquette, et al., 1986liquid phase; solvent: Hexane

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Liebman, Paquette, et al., 1986
Liebman, J.F.; Paquette, L.A.; Peterson, J.R.; Rogers, D.W., Is triquinacene homoaromatic? A thermochemical answer in the affirmative, J. Am. Chem. Soc., 1986, 108, 8267-8268. [all data]


Notes

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