Cobalt ion (1+)


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 51 to 73

(Cobalt ion (1+) • 2cobalt) + cobalt = (Cobalt ion (1+) • 3cobalt)

By formula: (Co+ • 2Co) + Co = (Co+ • 3Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
205. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 3cobalt) + cobalt = (Cobalt ion (1+) • 4cobalt)

By formula: (Co+ • 3Co) + Co = (Co+ • 4Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
274. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 4cobalt) + cobalt = (Cobalt ion (1+) • 5cobalt)

By formula: (Co+ • 4Co) + Co = (Co+ • 5Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
319. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 5cobalt) + cobalt = (Cobalt ion (1+) • 6cobalt)

By formula: (Co+ • 5Co) + Co = (Co+ • 6Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
283. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 6cobalt) + cobalt = (Cobalt ion (1+) • 7cobalt)

By formula: (Co+ • 6Co) + Co = (Co+ • 7Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
303. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 7cobalt) + cobalt = (Cobalt ion (1+) • 8cobalt)

By formula: (Co+ • 7Co) + Co = (Co+ • 8Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
283. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 8cobalt) + cobalt = (Cobalt ion (1+) • 9cobalt)

By formula: (Co+ • 8Co) + Co = (Co+ • 9Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
285. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • cobalt) + cobalt = (Cobalt ion (1+) • 2cobalt)

By formula: (Co+ • Co) + Co = (Co+ • 2Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
201. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + Deuterium = (Cobalt ion (1+) • Deuterium)

By formula: Co+ + D2 = (Co+ • D2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
71.5 (+6.7,-0.) CIDHaynes and Armentrout, 1996gas phase; guided ion beam CID; M

Cobalt ion (1+) + Propane = (Cobalt ion (1+) • Propane)

By formula: Co+ + C3H8 = (Co+ • C3H8)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
129. (+5.9,-0.) CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

Cobalt ion (1+) + cobalt = (Cobalt ion (1+) • cobalt)

By formula: Co+ + Co = (Co+ • Co)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
267. CIDArmentrout and Kickel, 1994gas phase; guided ion beam CID; M

(Cobalt ion (1+) • 2Ethane) + Ethane = (Cobalt ion (1+) • 3Ethane)

By formula: (Co+ • 2C2H6) + C2H6 = (Co+ • 3C2H6)

Quantity Value Units Method Reference Comment
Δr50.kJ/molSIDTKemper, Bushnell, et al., 1993gas phase; ΔrH<; M

(Cobalt ion (1+) • 2Ammonia) + Ammonia = (Cobalt ion (1+) • 3Ammonia)

By formula: (Co+ • 2H3N) + H3N = (Co+ • 3H3N)

Quantity Value Units Method Reference Comment
Δr64.0 ± 5.9kJ/molCIDTWalter and Armentrout, 1998RCD

(Cobalt ion (1+) • 3Ammonia) + Ammonia = (Cobalt ion (1+) • 4Ammonia)

By formula: (Co+ • 3H3N) + H3N = (Co+ • 4H3N)

Quantity Value Units Method Reference Comment
Δr49.0 ± 5.9kJ/molCIDTWalter and Armentrout, 1998RCD

(Cobalt ion (1+) • Ethylene) + Ethylene = (Cobalt ion (1+) • 2Ethylene)

By formula: (Co+ • C2H4) + C2H4 = (Co+ • 2C2H4)

Quantity Value Units Method Reference Comment
Δr152. ± 14.kJ/molCIDTSievers, Jarvis, et al., 1998RCD

(Cobalt ion (1+) • Pyrrole) + Pyrrole = (Cobalt ion (1+) • 2Pyrrole)

By formula: (Co+ • C4H5N) + C4H5N = (Co+ • 2C4H5N)

Quantity Value Units Method Reference Comment
Δr194.kJ/molRAKGapeev and Yang, 2000RCD

Cobalt ion (1+) + Methylene = (Cobalt ion (1+) • Methylene)

By formula: Co+ + CH2 = (Co+ • CH2)

Quantity Value Units Method Reference Comment
Δr318. ± 5.0kJ/molCIDTHaynes and Armentrout, 1994RCD

Cobalt ion (1+) + Pyridine = (Cobalt ion (1+) • Pyridine)

By formula: Co+ + C5H5N = (Co+ • C5H5N)

Quantity Value Units Method Reference Comment
Δr247. ± 13.kJ/molCIDTRodgers, Stanley, et al., 2000RCD

Cobalt ion (1+) + 1,3-Diazine = (Cobalt ion (1+) • 1,3-Diazine)

By formula: Co+ + C4H4N2 = (Co+ • C4H4N2)

Quantity Value Units Method Reference Comment
Δr245. ± 13.kJ/molCIDTAmunugama and Rodgers, 2001RCD

Cobalt ion (1+) + Adenine = (Cobalt ion (1+) • Adenine)

By formula: Co+ + C5H5N5 = (Co+ • C5H5N5)

Quantity Value Units Method Reference Comment
Δr293. ± 10.kJ/molCIDTRodgers and Armentrout, 2002RCD

Cobalt ion (1+) + Methyl Alcohol = (Cobalt ion (1+) • Methyl Alcohol)

By formula: Co+ + CH4O = (Co+ • CH4O)

Quantity Value Units Method Reference Comment
Δr148. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Cobalt ion (1+) + Argon = (Cobalt ion (1+) • Argon)

By formula: Co+ + Ar = (Co+ • Ar)

Quantity Value Units Method Reference Comment
Δr49.4kJ/molPDisAsher, Bellert, et al., 1994RCD

Cobalt ion (1+) + Pyrrole = (Cobalt ion (1+) • Pyrrole)

By formula: Co+ + C4H5N = (Co+ • C4H5N)

Quantity Value Units Method Reference Comment
Δr>280.kJ/molRAKGapeev and Yang, 2000RCD

References

Go To: Top, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Armentrout and Kickel, 1994
Armentrout, P.B.; Kickel, B.L., Gas Phase Thermochemistry of Transition Metal Ligand Systems: Reassessment of Values and Periodic Trends, in Organometallic Ion Chemistry, B. S. Freiser, ed, 1994. [all data]

Haynes and Armentrout, 1996
Haynes, C.L.; Armentrout, P.B., Guided Ion Beam Determination of the Co+ - H2 Bond Dissociation energy, Chem Phys. Let., 1996, 249, 1-2, 64, https://doi.org/10.1016/0009-2614(95)01337-7 . [all data]

Kemper, Bushnell, et al., 1993
Kemper, P.R.; Bushnell, J.; Von Koppen, P.; Bowers, M.T., Binding Energies of Co+(H2/CH4/C2H6)1,2,3 Clusters, J. Phys. Chem., 1993, 97, 9, 1810, https://doi.org/10.1021/j100111a016 . [all data]

Walter and Armentrout, 1998
Walter, D.; Armentrout, P.B., Periodic Trends in Chemical Reactivity: Reactions of Sc+, Y+, La+, and Lu+ with H2, D2 and HD, J. Am. Chem. Soc., 1998, 120, 13, 3176, https://doi.org/10.1021/ja973202c . [all data]

Sievers, Jarvis, et al., 1998
Sievers, M.R.; Jarvis, L.M.; Armentrout, P.B., Transition Metal Ethene Bonds: Thermochemistry of M+(C2H4)n (M=Ti-Cu, n=1 and 2) Complexes, J. Am. Chem. Soc., 1998, 120, 8, 1891, https://doi.org/10.1021/ja973834z . [all data]

Gapeev and Yang, 2000
Gapeev, A.; Yang, C.-N., Binding Energies of Gas-Phase Ions with Pyrrole. Experimental and Quantum Chemical Results, J. Phys. Chem. A, 2000, 104, 14, 3246, https://doi.org/10.1021/jp992627d . [all data]

Haynes and Armentrout, 1994
Haynes, C.L.; Armentrout, P.B., Thermochemistry and Structures of CoC3H6+: Metallacyclic and Metal-Alkene Isomers, Organomettalics, 1994, 13, 9, 3480, https://doi.org/10.1021/om00021a022 . [all data]

Rodgers, Stanley, et al., 2000
Rodgers, M.T.; Stanley, J.R.; Amunugama, R., Periodic Trends in the Binding of Metal Ions to Pyridine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Am. Chem. Soc., 2000, 122, 44, 10969, https://doi.org/10.1021/ja0027923 . [all data]

Amunugama and Rodgers, 2001
Amunugama, R.; Rodgers, M.T., Periodic Trends in the Binding of Metal Ions to Pyrimidine Studied by Threshold Collision-Induced Dissociation and Density Functional Theory, J. Phys. Chem. A, 2001, 105, 43, 9883, https://doi.org/10.1021/jp010663i . [all data]

Rodgers and Armentrout, 2002
Rodgers, M.T.; Armentrout, P.B., Influence of d orbital occupation on the binding of metal ions to adenine, J. Am. Chem. Soc., 2002, 124, 11, 2678, https://doi.org/10.1021/ja011278+ . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Asher, Bellert, et al., 1994
Asher, R.L.; Bellert, D.; Buthelezi, T.; Brucat, P.J., The Bond Strength of Ni2+, Chem. Phys. Lett., 1994, 224, 5-6, 529, https://doi.org/10.1016/0009-2614(94)00574-5 . [all data]


Notes

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