Monofluoroamine

Formula: FH₂N
Molecular weight: 35.0210
IUPAC Standard InChI: InChI=1S/FH2N/c1-2/h2H2
IUPAC Standard InChIKey: MDQRDWAGHRLBPA-UHFFFAOYSA-N
CAS Registry Number: 15861-05-9
Chemical structure:
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Vibrational and/or electronic energy levels

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Data compiled by: Marilyn E. Jacox

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


a'	1	NH₂ s-stretch	3269	H	Ar	IR	Andrews and Lascola, 1987
	1	NH₂ s-stretch	3234		N₂	IR	Baumgartel, Jochims, et al., 1989
	2	NH₂ scissors	1568	H	Ar	IR	Andrews and Lascola, 1987
	2	NH₂ scissors	1564		N₂	IR	Baumgartel, Jochims, et al., 1989
	3	NH₂ wag	1244	H	Ar	IR	Andrews and Lascola, 1987
	3	NH₂ wag	1241		N₂	IR	Baumgartel, Jochims, et al., 1989
	3	NH₂ wag	1233		N₂	IR	Baumgartel, Jochims, et al., 1989
	4	NF stretch	934	H	Ar	IR	Andrews and Lascola, 1987
	4	NF stretch	891		N₂	IR	Baumgartel, Jochims, et al., 1989
a	5	NH₂ a-stretch	3346		N₂	IR	Baumgartel, Jochims, et al., 1989

Additional references: Jacox, 1994, page 153; Christen, Minkwitz, et al., 1987

Notes

(1/2)(2ν)

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Andrews and Lascola, 1987
Andrews, L.; Lascola, R., Infrared spectra of the ammonia-fluorine and fluoramide-hydrogen fluoride complexes in solid argon, J. Am. Chem. Soc., 1987, 109, 21, 6243, https://doi.org/10.1021/ja00255a004 . [all data]

Baumgartel, Jochims, et al., 1989
Baumgartel, H.; Jochims, H.-W.; Ruhl, E.; Bock, H.; Dammel, R.; Minkwitz, J.; Nass, R., Photoelectron and photoionization mass spectra of the fluoramines NH₃-_nF_n¹, Inorg. Chem., 1989, 28, 943. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Christen, Minkwitz, et al., 1987
Christen, D.; Minkwitz, R.; Nass, R., Microwave spectrum, inversion, and molecular structure of monofluoramine, FNH2, J. Am. Chem. Soc., 1987, 109, 23, 7020, https://doi.org/10.1021/ja00257a019 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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