Phosphorocyanidous difluoride
- Formula: CF2NP
- Molecular weight: 94.9880
- IUPAC Standard InChI: InChI=1S/CF2NP/c2-5(3)1-4
- IUPAC Standard InChIKey: OOZKJXCTKSNMBV-UHFFFAOYSA-N
- CAS Registry Number: 14118-40-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Difluorocyanophosphine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.7 ± 0.2 | EI | Harland, Rankin, et al., 1974 | |
| 11.9 ± 0.1 | PE | Cradock and Rankin, 1972 | Vertical value |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| CNFP+ | 15.7 ± 0.2 | F | EI | Harland, Rankin, et al., 1974 | |
| CN+ | 19.8 ± 0.3 | PF2 | EI | Harland, Rankin, et al., 1974 | |
| FP+ | 19.1 ± 0.2 | F+CN | EI | Harland, Rankin, et al., 1974 | |
| F2P+ | 13.4 ± 0.2 | CN | EI | Harland, Rankin, et al., 1974 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Harland, Rankin, et al., 1974
Harland, P.W.; Rankin, D.W.H.; Thynne, J.C.J.,
Ionisation by electron impact of phosphorus trifluoride and difluorocyanophosphine,
Int. J. Mass Spectrom. Ion Phys., 1974, 13, 395. [all data]
Cradock and Rankin, 1972
Cradock, S.; Rankin, D.W.H.,
Photoelectron spectra of PF2H some substituted difluorophosphines,
J. Chem. Soc. Faraday Trans. 2, 1972, 68, 940. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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