Rhenium, pentacarbonyliodo-

Formula: C₅IO₅Re
Molecular weight: 453.162
IUPAC Standard InChI: InChI=1S/5CO.HI.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
IUPAC Standard InChIKey: DGSSBNZHZQWZBU-UHFFFAOYSA-M
CAS Registry Number: 13821-00-6
Chemical structure:
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Other names: Rhenium, pentacarbonyliodo-, (OC-6-22)-; Pentacarbonyliodorhenium
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Other data available:
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Gas phase ion energetics data

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV)	Method	Reference	Comment
8.64 ± 0.03	EI	Junk, Svec, et al., 1968	RDSH
8.36	PE	Higginson, Lloyd, et al., 1975	Vertical value; LLK
8.32	PE	Hall, 1975	Vertical value; LLK
8.50	PE	Ceasar, Milazzo, et al., 1974	Vertical value; LLK

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
COIRe⁺	16.69	4CO	EI	Junk, Svec, et al., 1968	RDSH
C₂O₂IRe⁺	14.65	3CO	EI	Junk, Svec, et al., 1968	RDSH
C₃O₃IRe⁺	12.04	2CO	EI	Junk, Svec, et al., 1968	RDSH
C₃O₃Re⁺	14.71	?	EI	Junk, Svec, et al., 1968	RDSH
C₄O₄IRe⁺	10.29	CO	EI	Junk, Svec, et al., 1968	RDSH
ReI⁺	19.20	5CO	EI	Junk, Svec, et al., 1968	RDSH
Re⁺	>23.	?	EI	Junk, Svec, et al., 1968	RDSH

References

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Junk, Svec, et al., 1968
Junk, G.A.; Svec, H.J.; Angelici, R.J., Electron impact studies of manganese and rhenium pentacarbonyl halides, J. Am. Chem. Soc., 1968, 90, 5758. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Hall, 1975
Hall, M.B., The use of spin-orbit coupling in the interpretation of photoelectron spectra. I. Application to substituted rhenium pentacarbonyls, J. Am. Chem. Soc., 1975, 97, 2057. [all data]

Ceasar, Milazzo, et al., 1974
Ceasar, G.P.; Milazzo, P.; Cihonski, J.L.; Levenson, R.A., Photoelectron spectra of osmium and ruthenium tetroxide, J. Am. Chem. Soc., 1974, 13, 3035. [all data]

Notes

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Symbols used in this document:

AE Appearance energy
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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