Difluoroborane

• Formula: BF₂H
• Molecular weight: 49.816
• IUPAC Standard InChI: InChI=1S/BF2H/c2-1-3/h1H Copy

  
• IUPAC Standard InChIKey: LRZMJFRZMNWFKE-UHFFFAOYSA-N Copy
• CAS Registry Number: 13709-83-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Computational Chemistry Comparison and Benchmark Database
• Options:
  • Switch to calorie-based units

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1998, page 238; Kasuya, Lafferty, et al., 1968; Westwood, Lewis-Bevan, et al., 1984

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Coyle, Ritter, et al., 1964
Coyle, T.D.; Ritter, J.J.; Farrar, T.C., Proc. Chem. Soc., 1964, 25. [all data]

Perec and Becka, 1965
Perec, M.; Becka, L.N., Infrared Spectra of Difluoroborane and Difluoroborane-d, J. Chem. Phys., 1965, 43, 2, 721, https://doi.org/10.1063/1.1696796 . [all data]

Lynds and Bass, 1965
Lynds, L.; Bass, C.D., Vibrational---Rotational Spectrum of Difluoroborane and Difluoroborane-d, J. Chem. Phys., 1965, 43, 12, 4357, https://doi.org/10.1063/1.1696697 . [all data]

Porter and Wason, 1965
Porter, R.F.; Wason, S.K., Reaction of Boroxine with BF3(g). Infrared Spectrum and Stability of HBF2(g), J. Phys. Chem., 1965, 69, 7, 2208, https://doi.org/10.1021/j100891a010 . [all data]

Shirk and Shirk, 1983
Shirk, A.E.; Shirk, J.S., Matrix isolation-mass spectroscopy study of the reaction of boron trifluoride with trimethylamine-alane and trimethylamine-gallane, Inorg. Chem., 1983, 22, 1, 72, https://doi.org/10.1021/ic00143a018 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kasuya, Lafferty, et al., 1968
Kasuya, T.; Lafferty, W.J.; Lide, D.R., Microwave Spectrum, Structure, Boron Quadrupole Coupling Constants, and Dipole Moment of Difluoroborane, J. Chem. Phys., 1968, 48, 1, 1, https://doi.org/10.1063/1.1664452 . [all data]

Westwood, Lewis-Bevan, et al., 1984
Westwood, N.P.C.; Lewis-Bevan, W.; Gerry, M.C.L., The microwave spectrum and centrifugal distortion constants of difluoroborane, HBF2, J. Mol. Spectrosc., 1984, 106, 1, 227, https://doi.org/10.1016/0022-2852(84)90095-X . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.