Diboron tetrachloride
- Formula: B2Cl4
- Molecular weight: 163.434
- IUPAC Standard InChI: InChI=1S/B2Cl4/c3-1(4)2(5)6
- IUPAC Standard InChIKey: LCWVIHDXYOFGEG-UHFFFAOYSA-N
- CAS Registry Number: 13701-67-2
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| ≤10.42 ± 0.02 | PE | Lynaugh, Lloyd, et al., 1972 | LLK |
| 10.32 ± 0.02 | PI | Dibeler and Walker, 1969 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| BCl+ | 13.71 ± 0.04 | BCl3 | PI | Dibeler and Walker, 1969 | RDSH |
| BCl2+ | 11.32 ± 0.02 | BCl2 | PI | Dibeler and Walker, 1969 | RDSH |
| B2Cl2+ | 17.24 ± 0.03 | 2Cl? | PI | Dibeler and Walker, 1969 | RDSH |
| B2Cl3+ | 11.52 ± 0.02 | Cl | PI | Dibeler and Walker, 1969 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lynaugh, Lloyd, et al., 1972
Lynaugh, N.; Lloyd, D.R.; Guest, M.F.; Hall, M.B.; Hillier, I.H.,
Photoelectron studies of boron compounds. Part 4. Experimental and theoretical studies of diboron and tetrachloride diboron tetrafluoride,
J. Chem. Soc. Faraday Trans. 2, 1972, 68. [all data]
Dibeler and Walker, 1969
Dibeler, V.H.; Walker, J.A.,
Mass spectrometric study of photoionization. XIII.Boron trichloride and diborontetrachloride,
Inorg. Chem., 1969, 8, 50. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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