2,5-Norbornadiene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid213.8 ± 3.0kJ/molCcbSteele, 1978ALS
Δfliquid178.7 ± 1.0kJ/molCcbHall, Smith, et al., 1973ALS
Quantity Value Units Method Reference Comment
Δcliquid-4111.7 ± 3.0kJ/molCcbSteele, 1978Corresponding Δfliquid = 213.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-4076.7 ± 1.0kJ/molCcbHall, Smith, et al., 1973Corresponding Δfliquid = 178.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-4099.kJ/molCcbSkuratov, Kozina, et al., 1958Corresponding Δfliquid = 201. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
161.2298.15Steele, 1978DH
116.1297.Hall, Smith, et al., 1973DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Steele, 1978
Steele, W.V., The standard enthalpies of formation of a series of C7, bridged-ring hydrocarbons: norbornane, norbornene, nortricyclene, norbornadiene, and quadricyclane, J. Chem. Thermodyn., 1978, 10, 919-927. [all data]

Hall, Smith, et al., 1973
Hall, H.K., Jr.; Smith, C.D.; Baldt, J.H., Enthalpies of formation of norticyclene, norbornene, norbornadiene, and quadricyclane, J. Am. Chem. Soc., 1973, 95, 3197-3201. [all data]

Skuratov, Kozina, et al., 1958
Skuratov, S.M.; Kozina, M.P.; Shtocher, S.M.; Prevalova, N.M.; Kamkina, L.S.; Zuko, V.D., Heats of combustion of cyclic compounds, Bull. Chem. Thermodyn., 1958, 1, 21. [all data]


Notes

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