Reaction data

1-Octene + Hydrogen = Octane


Enthalpy of reaction at standard conditions (nominally 298.15 K, 1 atm.)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

ΔrH° (kcal/mol) Method Reference Comment
-30.02 ± 0.29ChydRogers, Dejroongruang, et al., 1992liquid phase; solvent: Cyclohexane; ALS
-29.67 ± 0.60ChydMolnar, Rachford, et al., 1984liquid phase; solvent: Dioxane; ALS
-29.95 ± 0.30ChydMolnar, Rachford, et al., 1984liquid phase; solvent: Hexane; ALS
-31.1 ± 1.4ChydLopes, Nunes, et al., 1975liquid phase; solvent: Acetic acid; ALS
-29.40 ± 0.34ChydRogers and Skanupong, 1974liquid phase; solvent: Hexane; ALS
-28.3 ± 0.6ChydRogers and McLafferty, 1971liquid phase; solvent: Hydrocarbon; ALS
-30.06 ± 0.26ChydBretschneider and Rogers, 1970liquid phase; solvent: glacial acetic acid; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Rogers, Dejroongruang, et al., 1992
Rogers, D.W.; Dejroongruang, K.; Samuel, S.D.; Fang, W.; Zhao, Y., Enthalpies of hydrogenation of the octenes and the methylheptenes, J. Chem. Thermodyn., 1992, 24, 561-565. [all data]

Molnar, Rachford, et al., 1984
Molnar, A.; Rachford, R.; Smith, G.V.; Liu, R., Heats of hydrogenation by a simple and rapid flow calorimetric method, Appl. Catal., 1984, 9, 219-223. [all data]

Lopes, Nunes, et al., 1975
Lopes, M.T.R.; Nunes, M.F.T.; Florencio, M.H.F.S.; Mota, M.M.G.; Fernandez, M.T.N., Heats of hydrogenation in solution. I. Calorimeter for semimicro determinations, Rev. Port. Quim., 1975, 15, 129-132. [all data]

Rogers and Skanupong, 1974
Rogers, D.W.; Skanupong, S., Heats of hydrogenation of sixteen terminal monoolefins. The alternating effect, J. Phys. Chem., 1974, 78, 2569-2572. [all data]

Rogers and McLafferty, 1971
Rogers, D.W.; McLafferty, F.J., A new hydrogen calorimeter. Heats of hydrogenation of allyl and vinyl unsaturation adjacent to a ring, Tetrahedron, 1971, 27, 3765-3775. [all data]

Bretschneider and Rogers, 1970
Bretschneider, E.; Rogers, D.W., A new microcalorimeter: heats of hydrogenation of four monoolefins, Mikrochim. Acta, 1970, 482-490. [all data]


Notes

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