Resorcinol

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil550.KN/ABuckingham and Donaghy, 1982BS
Tboil549.1KN/AKrupatkin and Rozhentsova, 1971Uncertainty assigned by TRC = 0.4 K; TRC
Tboil554.55KN/ALecat, 1943Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus384. ± 5.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple383.54KN/ASabbah and Buluku, 1991Crystal phase 1 phase; Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple382.7KN/AEbisuzaki, Askari, et al., 1987Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Ttriple382.8KN/AAndrews, Lynn, et al., 1926Uncertainty assigned by TRC = 0.25 K; obtained from cooling curve in absence of air; TRC
Quantity Value Units Method Reference Comment
Δvap18.7 ± 0.31kcal/molN/AVerevkin and Kozlova, 2008AC
Quantity Value Units Method Reference Comment
Δsub20.55 ± 0.12kcal/molCSabbah and Buluku, 1991, 2ΔHfusion =15.25±0.52 kJ/mol; ALS
Δsub20.6kcal/molN/ASabbah and Buluku, 1991, 2DRB
Δsub20.9 ± 0.1kcal/molCSabbah and Buluku, 1991, 2AC
Δsub22.2kcal/molN/ADesai, Wilhoit, et al., 1968DRB

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
451.20.021Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
17.8434.AStephenson and Malanowski, 1987Based on data from 419. to 550. K.; AC
17.8407.GCStephenson and Malanowski, 1987Based on data from 392. to 463. K. See also Kundel, Lille, et al., 1975.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
424.7 to 549.75.516772687.152-62.164von Terres, Gebert, et al., 1955Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
20.4 ± 0.1334.CSabbah and Buluku, 1991, 2AC
22.1353.GSBender, Bieling, et al., 1983Based on data from 328. to 379. K.; AC
22.3 ± 5.0324. to 335.N/ADesai, Wilhoit, et al., 1968AC
22.3303.N/AHoyer and Peperle, 1958Based on data from 283. to 323. K.; AC
22.8 ± 0.3329.VWolf and Weghofer, 1938ALS

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Method Reference Comment
4.8996381.N/AViikna, Gambino, et al., 1982DH
4.52382.6N/ABret-Dibat and Lichanot, 1989AC
5.0908382.8N/AAndrews, Lynn, et al., 1926, 2DH
5.09382.9CAndrews, Lynn, et al., 1926, 2AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
12.9381.Viikna, Gambino, et al., 1982DH
13.3382.8Andrews, Lynn, et al., 1926, 2DH

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
0.782366.8Bret-Dibat and Lichanot, 1989, 2CAL
11.81382.6

Enthalpy of phase transition

ΔHtrs (kcal/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.3274369.crystaline, IIcrystaline, IEbisuzaki, Askari, et al., 1987, 2DH
4.9928382.7crystaline, IliquidEbisuzaki, Askari, et al., 1987, 2DH
0.2868366.75crystaline, IIcrystaline, IBret-Dibat and Lichanot, 1989DH
4.5172382.55crystaline, IliquidBret-Dibat and Lichanot, 1989DH

Entropy of phase transition

ΔStrs (cal/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.887369.crystaline, II, àcrystaline, I, á phase transitionEbisuzaki, Askari, et al., 1987, 2DH
13.05382.7crystaline, I, Fusion of áliquid, resorcinolEbisuzaki, Askari, et al., 1987, 2DH
0.79366.75crystaline, IIcrystaline, IBret-Dibat and Lichanot, 1989DH
14.382.55crystaline, IliquidBret-Dibat and Lichanot, 1989DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Buckingham and Donaghy, 1982
Buckingham, J.; Donaghy, S.M., Dictionary of Organic Compounds: Fifth Edition, Chapman and Hall, New York, 1982, 1. [all data]

Krupatkin and Rozhentsova, 1971
Krupatkin, I.L.; Rozhentsova, E.P., Some properties of systems with latent liquid immiscibility, Russ. J. Phys. Chem. (Engl. Transl.), 1971, 45, 1700. [all data]

Lecat, 1943
Lecat, M., Azeotropes of Ethyl Urethane and other Azeotropes, C. R. Hebd. Seances Acad. Sci., 1943, 217, 273. [all data]

Sabbah and Buluku, 1991
Sabbah, R.; Buluku, E.N.L.E., Thermodynamic stury of the three isomers of dihydroxybenzene, Can. J. Chem., 1991, 69, 481. [all data]

Ebisuzaki, Askari, et al., 1987
Ebisuzaki, Y.; Askari, L.H.; Bryan, A.M., Phase transitions in resorcinol, J. Chem. Phys., 1987, 87, 6659-64. [all data]

Andrews, Lynn, et al., 1926
Andrews, D.H.; Lynn, G.; Johnston, J., The Heat Capacities and Heat of Crystallization of Some Isomeric Aromatic Compounds, J. Am. Chem. Soc., 1926, 48, 1274. [all data]

Verevkin and Kozlova, 2008
Verevkin, Sergey P.; Kozlova, Svetlana A., Di-hydroxybenzenes: Catechol, resorcinol, and hydroquinone, Thermochimica Acta, 2008, 471, 1-2, 33-42, https://doi.org/10.1016/j.tca.2008.02.016 . [all data]

Sabbah and Buluku, 1991, 2
Sabbah, R.; Buluku, E.N.L.E., Thermodynamic study of three isomers of dihydroxybenzene, Can. J. Chem., 1991, 69, 481-488. [all data]

Desai, Wilhoit, et al., 1968
Desai, P.D.; Wilhoit, R.C.; Zwolinski, B.J., Heat of combustion of resorcinol and enthalpies of isomerization of dihydroxybenzenes, J. Chem. Eng. Data, 1968, 13, 334-335. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kundel, Lille, et al., 1975
Kundel, H.; Lille, U.; Kaidas, N., Tr. Tallin. Politekh. Inst., 1975, 390, 107. [all data]

von Terres, Gebert, et al., 1955
von Terres, E.; Gebert, F.; Hulsemann, H.; Petereit, H.; Toepsch, H.; Ruppert, W., Zur Kenntnis der physikalisch-chemischen Grundlagen der Gewinnung und Zerlegung der Phenolfraktionen von Steinkohlenteer und Braunkohlenschwelteer. IV. Mitteilung Die Dampfdrucke von Phenol und Phenolderivaten, Brennst.-Chem., 1955, 36, 272-274. [all data]

Bender, Bieling, et al., 1983
Bender, R.; Bieling, V.; Maurer, G., The vapour pressures of solids: anthracene, hydroquinone, and resorcinol, The Journal of Chemical Thermodynamics, 1983, 15, 6, 585-594, https://doi.org/10.1016/0021-9614(83)90058-7 . [all data]

Hoyer and Peperle, 1958
Hoyer, H.; Peperle, W., Z. Elektrochem., 1958, 62, 61. [all data]

Wolf and Weghofer, 1938
Wolf, K.L.; Weghofer, H., Uber sublimationswarmen, Z. Phys. Chem., 1938, 39, 194-208. [all data]

Viikna, Gambino, et al., 1982
Viikna, A.; Gambino, M.; Pouzard, G.; Bros, J.P., Determination of partial enthalpies of mixing at infinite dilution of orcinol and resorcinol in water, dibutyl ether and diisopropyl ether, Calorim. Anal. Therm., 1982, 13, III. [all data]

Bret-Dibat and Lichanot, 1989
Bret-Dibat, P.; Lichanot, A., Thermodynamic properties of positional isomers of disubstituted benzene in condensed phase, Thermochim. Acta, 1989, 147(2), 261-271. [all data]

Andrews, Lynn, et al., 1926, 2
Andrews, D.H.; Lynn, G.; Johnston, J., The heat capacities and heat of crystallization of some isomeric aromatic compounds, J. Am. Chem. Soc., 1926, 48, 1274-1287. [all data]

Bret-Dibat and Lichanot, 1989, 2
Bret-Dibat, P.; Lichanot, A., Proprietes thermodynamiques des isomeres de position de benzenes disubstitues en phase condensee, Thermochim. Acta, 1989, 147, 2, 261, https://doi.org/10.1016/0040-6031(89)85181-0 . [all data]

Ebisuzaki, Askari, et al., 1987, 2
Ebisuzaki, Y.; Askari, L.H.; Bryan, A.M., Phase transitions in resorcinol, J. Chem. Phys., 1987, 87, 6659-6664. [all data]


Notes

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