Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Styrene

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Condensed phase thermochemistry data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - H.Y. Afeefy, J.F. Liebman, and S.E. Stein
DRB - D.R. Burgess
DH - E.S. Domalski and E.D. Hearing

QuantityValueUnitsMethodReferenceComment
Deltafliquid103.4 ± 0.92kJ/molCcbProsen and Rossini, 1945ALS
Deltafliquid108.kJ/molCcbLandrieu, Baylocq, et al., 1929ALS
Deltafliquid87.6 ± 4.0kJ/molCcbN/Arecalculated with modern CO2,H2O thermo; estimated uncertainty (NOTE all values in source also have wrong sign); DRB
Deltafliquid-58.6kJ/molCcbMoureu and Andre, 1914ALS
QuantityValueUnitsMethodReferenceComment
Deltacliquid-4390. ± 60.kJ/molAVGN/AAverage of 9 values; Individual data points
QuantityValueUnitsMethodReferenceComment
liquid240.5J/mol*KN/AWarfield and Petree, 1961DH
liquid237.57J/mol*KN/APitzer, Guttman, et al., 1946DH
liquid237.6J/mol*KN/AGuttman and Westrum, 1943DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K)Temperature (K)ReferenceComment
183.2298.15Lebedev, Lebedev, et al., 1985DH
182.6298.16Warfield and Petree, 1961T = 10 to 300 K.; DH
235.6298.Kurbatov, 1950T = 21 to 139 C.; DH
182.84298.15Pitzer, Guttman, et al., 1946T = 15 to 300 K.; DH
179.9298.5Smith and Andrews, 1931T = 102 to 299 K. Value is unsmoothed experimental datum.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Prosen and Rossini, 1945
Prosen, E.J.; Rossini, F.D., Heats of formation and combustion of 1,3-butadiene and styrene, J. Res. NBS, 1945, 34, 59-63. [all data]

Landrieu, Baylocq, et al., 1929
Landrieu, P.; Baylocq, F.; Johnson, J.R., Etude thermochimique dans la serie furanique, Bull. Soc. Chim. France, 1929, 45, 36-49. [all data]

Moureu and Andre, 1914
Moureu, C.; Andre, E., Thermochimie des composes acetyleniques, Ann. Chim. Phys., 1914, 1, 113-145. [all data]

Warfield and Petree, 1961
Warfield, R.W.; Petree, M.C., Thermodynamic properties of polystyrene and styrene, J. Polymer Sci., 1961, 55, 497-505. [all data]

Pitzer, Guttman, et al., 1946
Pitzer, K.S.; Guttman, L.; Westrum, E.F., Jr., The heat capacity, heats of fusion and vaporization, vapor pressure, entropy vibration frequencies and barrier to internal rotation of styrene, J. Am. Chem. Soc., 1946, 68, 2209-2212. [all data]

Guttman and Westrum, 1943
Guttman, L.; Westrum, E.F., Jr., and Pitzer, K.S., The thermodynamics of styrene (phenylethylene), including equilibrium of formation from ethylbenzene, J. Am. Chem. Soc., 1943, 65, 1246-1247. [all data]

Lebedev, Lebedev, et al., 1985
Lebedev, B.V.; Lebedev, N.K.; Smirnova, N.N.; Kozyreva, N.M.; Kirillin, A.I.; Korshak, V.V., The isotope effect in the thermodynamic parameters of polymerization of styrene, Dokl. Akad. Nauk, 1985, SSSR 281, 379-383. [all data]

Kurbatov, 1950
Kurbatov, V.Ya., Specific heats of liquids. III. Specific heat of hydrocarbons with several noncondensed rings, Zhur. Obshch. Khim., 1950, 20, 1139-1144. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. I. Phenyl derivatives of methane, ethane and some related compounds. J. Am. Chem. Soc., 1931, 53, 3644-3660. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, References