PO3 anion

• Formula: O₃P^-
• Molecular weight: 78.9725
• CAS Registry Number: 15389-19-2
• Information on this page:
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

O₃P^- +  = (O₃P^- • )

By formula: O₃P^- + H₂O = (O₃P^- • H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(O₃P^- • ) +  = (O₃P^- • 2)

By formula: (O₃P^- • H₂O) + H₂O = (O₃P^- • 2H₂O)

Bond type: Hydrogen bond (negative ion to hydride)

(O₃P^- • 2) +  = (O₃P^- • 3)

By formula: (O₃P^- • 2H₂O) + H₂O = (O₃P^- • 3H₂O)

(O₃P^- • 3) +  = (O₃P^- • 4)

By formula: (O₃P^- • 3H₂O) + H₂O = (O₃P^- • 4H₂O)

(O₃P^- • 4294967295) +  = O₃P^-

By formula: (O₃P^- • 4294967295O₂P) + O₂P = O₃P^-

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Keesee and Castleman Jr., 1989
Keesee, R.G.; Castleman Jr., Hydration of Monomeric Metaphosphate Anion in the Gas Phase, J. Am. Chem. Soc., 1989, 111, 25, 9015, https://doi.org/10.1021/ja00207a004 . [all data]

Blades, Ho, et al., 1996
Blades, A.T.; Ho, Y.; Kebarle, P., Hydration in the Gas Phase of the Orthophosphate Anion (HO)2PO2-, and the Conversion of the Orthophosphate anion to the Metaphosphate, PO3-, Ion, J. Am. Chem. Soc., 1996, 118, 1, 196, https://doi.org/10.1021/ja952169w . [all data]

Blades, Ho, et al., 1996, 2
Blades, A.T.; Ho, Y.; Kebarle, P., Hydration in the Gas Phase of the Orthophosphate Anion, (HO)2PO2-, and the Conversion of the Orthophosphate to teh Metaphosphate, PO3-, Ion, J. Am. Chem. Soc., 1996, 118, 1, 196, https://doi.org/10.1021/ja952169w . [all data]

Wang and Wang, 1999
Wang, X.B.; Wang, L.S., Vibrationally resolved photoelectron spectroscopy of PO3- and the electronic structure of PO3, Chem. Phys. Lett., 1999, 313, 1-2, 179-183, https://doi.org/10.1016/S0009-2614(99)00993-8 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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