NiC=CH2

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td Ar 280 360 Kline, Kafafi, et al., 1987

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 CH2 s-stretch 2889.1 Ar IR Kline, Kafafi, et al., 1987
2 C=C stretch 1635.0 Ar IR Kline, Kafafi, et al., 1987
b1 6 H2CC OPLA 758.6 Ar IR Kline, Kafafi, et al., 1987
b2 8 CH2 a-stretch 2983.5 Ar IR Kline, Kafafi, et al., 1987
9 CH2 rock 833.6 Ar IR Kline, Kafafi, et al., 1987

Additional references: Jacox, 1994, page 245

Notes

dPhotodissociation threshold

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kline, Kafafi, et al., 1987
Kline, E.S.; Kafafi, Z.H.; Hauge, R.H.; Margrave, J.L., FTIR matrix isolation studies of the reactions of atomic and diatomic nickel with acetylene in solid argon. The photosynthesis of nickel vinylidene, J. Am. Chem. Soc., 1987, 109, 8, 2402, https://doi.org/10.1021/ja00242a025 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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