t-ClC(O)OO
- Formula: CClO3
- Molecular weight: 95.462
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 43500 | Ne | Pernice, Garcia, et al., 2004 | |||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| a' | 1 | C=O stretch | 1886 | m s | Ar | IR | Pernice, Garcia, et al., 2004 |
| 2 | O-O stretch | 1072 | w | Ar | IR | Pernice, Garcia, et al., 2004 | |
| 3 | C-O stretch | 925 | vs | Ar | IR | Pernice, Garcia, et al., 2004 | |
| 4 | CCl stretch | 809 | w m | Ar | IR | Pernice, Garcia, et al., 2004 | |
| 5 | ClCO deform. | 504 | w | Ar | IR | Pernice, Garcia, et al., 2004 | |
| a | 8 | ClCOO2 OPLA | 614 | w m | Ar | IR | Pernice, Garcia, et al., 2004 |
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| vs | Very strong |
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pernice, Garcia, et al., 2004
Pernice, H.; Garcia, P.; Willner, H.; Francisco, J.S.; Mills, F.P.; Allen, M.; Yung, Y.L.,
Laboratory evidence for a key intermediate in the Venus atmosphere: Peroxychloroformyl radical,
Proc. Nat. Acad. Sci., 2004, 101, 39, 14007, https://doi.org/10.1073/pnas.0405501101
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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