Krypton
- Formula: Kr
- Molecular weight: 83.798
- IUPAC Standard InChIKey: DNNSSWSSYDEUBZ-UHFFFAOYSA-N
- CAS Registry Number: 7439-90-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Kr; UN 1056; UN 1970
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- NIST Atomic Spectra Database - Lines Holdings (on physics web site)
- NIST Atomic Spectra Database - Levels Holdings (on physics web site)
- NIST Atomic Spectra Database - Ground states and ionization energies (on physics web site)
- Gas Phase Kinetics Database
- X-ray Photoelectron Spectroscopy Database, version 5.0
- X-ray Photoelectron Spectroscopy Database, version 5.0
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase thermochemistry data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
S°gas,1 bar | 164.085 ± 0.003 | J/mol*K | Review | Cox, Wagman, et al., 1984 | CODATA Review value |
S°gas,1 bar | 164.08 | J/mol*K | Review | Chase, 1998 | Data last reviewed in March, 1982 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | 298. to 6000. |
---|---|
A | 20.78603 |
B | 4.850638×10-10 |
C | -1.582916×10-10 |
D | 1.525102×10-11 |
E | 3.196347×10-11 |
F | -6.197341 |
G | 189.2390 |
H | 0.000000 |
Reference | Chase, 1998 |
Comment | Data last reviewed in March, 1982 |
Phase change data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 119.78 | K | N/A | Ziegler, Yarbrough, et al., 1964 | Uncertainty assigned by TRC = 0.05 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 115.76 | K | N/A | Ziegler, Yarbrough, et al., 1964 | Uncertainty assigned by TRC = 0.08 K; TRC |
Ttriple | 116.1 | K | N/A | Lahr and Eversole, 1962 | Uncertainty assigned by TRC = 0.4 K; TRC |
Ttriple | 115.95 | K | N/A | Clusius and Weigand, 1940 | Uncertainty assigned by TRC = 0.2 K; See property X for dP/dT for c-l equil.; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.7315 | bar | N/A | Ziegler, Yarbrough, et al., 1964 | Uncertainty assigned by TRC = 0.0006 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 209.46 | K | N/A | Theeuwes and Bearman, 1970 | Uncertainty assigned by TRC = 0.02 K; PVT, VP measured up to 208 K. Tc from rect plot, equation. PRT, IPTS-48, PB with differential press. indicator, glc sensitive to 20 ppm impurity, none found.; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 55.2019 | bar | N/A | Theeuwes and Bearman, 1970 | Uncertainty assigned by TRC = 0.0551 bar; from Vapor pressure equation; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 11.0 | mol/l | N/A | Theeuwes and Bearman, 1970 | Uncertainty assigned by TRC = 0.109 mol/l; TRC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
126.68 to 208. | 4.2064 | 539.004 | 8.855 | Theeuwes and Bearman, 1970, 2 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Cox, Wagman, et al., 1984
Cox, J.D.; Wagman, D.D.; Medvedev, V.A.,
CODATA Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984, 1. [all data]
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Ziegler, Yarbrough, et al., 1964
Ziegler, W.T.; Yarbrough, D.W.; Mullins, J.C.,
Calculation of the Vapor Pressure and Heats of Vaporization and Sublimation of Liquids and Solids below One Atmosphere Pressure. VI. Krypton, Ga. Inst. Technol., Eng. Exp. Stn., Proj. A-764, Tech. Rep. No. 1, 1964. [all data]
Lahr and Eversole, 1962
Lahr, P.H.; Eversole, W.G.,
Compression Isotherms of Argon, Krypton, and Xenon Through the Freezing Zone,
J. Chem. Eng. Data, 1962, 7, 42-47. [all data]
Clusius and Weigand, 1940
Clusius, K.; Weigand, K.,
Melting Curves of the Gases A, Kr, Xe, CH4, CH3D, CD4, C2H4, C2H6, COS, and PH3 to 200 Atmospheres Pressure. The Chane of Volume on Melting,
Z. Phys. Chem., Abt. B, 1940, 46, 1-37. [all data]
Theeuwes and Bearman, 1970
Theeuwes, F.; Bearman, R.J.,
The p,V,T behaviour of dense fluids III. The vapor pressure and orthobaric densities of krypton,
J. Chem. Thermodyn., 1970, 2, 179-85. [all data]
Theeuwes and Bearman, 1970, 2
Theeuwes, F.; Bearman, R.J.,
The p,V,T Behavior of Dense Fluids. III. The Vapor Pressure and Orthobaric Density of Krypton,
J. Chem. Thermodyn., 1970, 2, 2, 179-185, https://doi.org/10.1016/0021-9614(70)90081-9
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Pc Critical pressure Ptriple Triple point pressure S°gas,1 bar Entropy of gas at standard conditions (1 bar) Tboil Boiling point Tc Critical temperature Ttriple Triple point temperature ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.